N-doped reduced graphene oxide promoted nano TiO2 as a bifunctional adsorbent/photocatalyst for CO2 photoreduction: Effect of N species

• Published in: Chemical engineering journal (Lausanne, Switzerland : 1996) Vol. 316; no. C; pp. 449 - 460
• Main Authors: Lin, Liang-Yi, Nie, Yao, Kavadiya, Shalinee, Soundappan, Thiagarajan, Biswas, Pratim
• Format: Journal Article
• Language: English
• Published: Switzerland Elsevier B.V 15.05.2017; Elsevier
• Subjects: CO2 capture; CO2 photoreduction; Graphene; Nano TiO2; Photocatalysis; Nano TiO2; CO2 capture; Graphene; CO2 photoreduction; Photocatalysis
• ISSN: 1385-8947; 1873-3212
• DOI: 10.1016/j.cej.2017.01.125

[Display omitted] •The N dopants play crucial roles on the photoactivity and stability of TiO2/NrGO.•Both quantity and bonding configuration of N are crucial for CO2 photoreduction.•Adequate N doping enhances the adsorption ability and charge separation efficiency. A series of TiO2/nitrogen (N) doped reduced graphene oxide (TiO2/NrGO) nanocomposites with varying concentration and bonding configurations of nitrogen were synthesized by a one-step urea-assisted hydrothermal method, and applied to photoreduction of CO2 with H2O vapor in the gas-phase under the irradiation of a Xe lamp. The effect of the N dopant (doping quantity and bonding configuration) on the catalytic performance of TiO2/NrGO was examined. In particular, TiO2/NrGO-300, with a 300:1mass ratio of urea/GO in precursor solution, had the highest CO production yield (356.5μmolg−1), manifesting a significant 4.4 and 2.2-fold enhancements of CO yield over pure TiO2 and TiO2/rGO, respectively. More significantly, TiO2/NrGO showed excellent catalytic stability during the prolonged reaction, while catalytic deactivation was observed for both pristine TiO2 and TiO2/rGO after a few hours. The promoting effects of N dopants on the structure and activity of TiO2/NrGO were investigated. It was demonstrated that NrGO with an appropriate N quantity and N-bonding configuration acted as a dual-functional promoter, simultaneously enhancing CO2 adsorption on the catalyst surface and facilitating electron-hole separation, while eventually boosted the photocatalytic performance. Experimental results in this work provide a better understanding of the critical roles of N dopants in the synthesized composites and also inspire the ongoing interest in better design of other N-doped graphene based materials for photoreduction of CO2.