Nanometer-scale Sn coatings improve the performance of silicon nanowire LIB anodes

• Published in: Journal of materials chemistry. A, Materials for energy and sustainability Vol. 2; no. 29; pp. 11261 - 11279
• Main Authors: Kohandehghan, Alireza, Cui, Kai, Kupsta, Martin, Memarzadeh, Elmira, Kalisvaart, Peter, Mitlin, David
• Format: Journal Article
• Language: English
• Published: 01.01.2014
• Subjects: Accumulators; Anodes; Coatings; Collectors; Cycles; Nanowires; Performance enhancement; Silicon
• ISSN: 2050-7488; 2050-7496
• DOI: 10.1039/c4ta00993b

We demonstrate that a thin partially dewetted coating of Sn will improve the cycling performance of silicon nanowire (SiNWs) lithium ion battery (LIB) anodes. The optimum architecture 3Sn/SiNWs (i.e. a Sn layer with an average film thickness of a 3 nm covering the nanowire) maintained a reversible capacity of 1865 mA h g-1 after 100 cycles at a rate of 0.1 C. This is almost double of the baseline uncoated SiNWs, where the reversible capacity after 100 cycles was 1046 mA h g-1 ( similar to 78% improvement). The 1Sn/SiNWs and 3Sn/SiNWs electrodes demonstrated much improved cycling coulombic efficiency, with >99% vs. 94-98% for the baseline. At a high current density of 5 C, these nanocomposite offered 2 the capacity retention of bare SiNWs ( similar to 20 vs. similar to 10% of 0.1 C capacity). It is demonstrated that the Sn coating both lithiates and delithiates at a higher voltage than Si and thus imparts a compressive stress around the nanowires. This confines their radial expansion in favor of longitudinal, and reduces the well-known failure mode by lithiation-induced nanowire stranding and fracture. TOF-SIMS analysis on the post-cycled delithiated specimens shows enhanced Li signal near the current collector due to accelerated SEI formation at the interface. FIB demonstrates concurrent en-masse delamination of SEI agglomerated sections of the nanowires from the current collector. Both of these deleterious effects are lessened by the presence of the Sn coatings.