Impact of the sintering parameters on the grain size, crystal phases, translucency, biaxial flexural strength, and fracture load of zirconia materials

• Published in: Journal of the mechanical behavior of biomedical materials Vol. 155; p. 106580
• Main Authors: Mayinger, Felicitas, Ender, Andreas, Strickstrock, Monika, Elsayed, Adham, Nassary Zadeh, Parissa, Zimmermann, Marcus, Stawarczyk, Bogna
• Format: Journal Article
• Language: English
• Published: Netherlands Elsevier Ltd 01.07.2024
• Subjects: Flexural Strength; High-speed sintering; Materials Testing; Mechanical Phenomena; Optical Phenomena; Particle Size; Speed-sintering; Stress, Mechanical; Zirconia; Zirconium - chemistry; Zirconia; Speed-sintering; High-speed sintering
• ISSN: 1751-6161; 1878-0180; 1878-0180
• DOI: 10.1016/j.jmbbm.2024.106580

To investigate the influence of the zirconia and sintering parameters on the optical and mechanical properties. Three zirconia materials (3/4Y-TZP, 4Y-TZP, 3Y-TZP) were high-speed (HSS), speed (SS) or conventionally (CS) sintered. Disc-shaped specimens nested in 4 vertical layers of the blank were examined for grain size (GS), crystal phases (c/t’/t/m-phase), translucency (T), and biaxial flexural strength. Fracture load (FL) of three-unit fixed dental prostheses was determined initially and after thermomechanical aging. Fracture types were classified, and data statistically analyzed. 4Y-TZP showed a higher amount of c + t’-phase and lower amount of t-phase, and higher optical and lower mechanical properties than 3Y-TZP. In all materials, T declined from Layer 1 to 4. 3/4Y-TZP showed the highest FL, followed by 3Y-TZP, while 4Y-TZP showed the lowest. In 4Y-TZP, the sintering parameters exercised a direct impact on GS and T, while mechanical properties were largely unaffected. The sintering parameters showed a varying influence on 3Y-TZP. Thermomechanical aging resulted in comparable or higher FL. 3/4Y-TZP presenting the highest FL underscores the principle of using strength-gradient multi-layer blanks to profit from high optical properties in the incisal area, while ensuring high mechanical properties in the lower areas subject to tensile forces. With all groups exceeding maximum bite forces, the examined three-unit FDPs showed promising long-term mechanical properties. [Display omitted] •4Y-TZP showed more c + t’-phase and less t-phase than 3Y-TZP.•4Y-TZP showed higher optical and lower mechanical properties than 3Y-TZP.•3/4Y-TZP showed higher fracture load values than 3Y-TZP or 4Y-TZP.•Sintering parameters showed direct impact on grain size and translucency of 4Y-TZP.•Mechanical properties of 4Y-TZP were largely unaffected by sintering parameters.