Lignin utilization: A review of lignin depolymerization from various aspects

• Published in: Renewable & sustainable energy reviews Vol. 107; pp. 232 - 249
• Main Authors: Chio, Chonlong, Sain, Mohini, Qin, Wensheng
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.06.2019
• Subjects: Biodegradation; Catalysis; Depolymerization; Lignin; Pyrolysis; β-O-4 cleavage; HL; Ca(OH)2; Al2O3; FeSO4; Depolymerization; LiOH; MA; HBT; Catalysis; SiO2; UV; Pyrolysis; GS-HPV; w.t.; VA; MnP; PCB; DDVA; p-TsOH; DyP; NaHS; VP; 5CVA; Lignin; C. echinulata; β-O-4 cleavage; NaOH; CsOH; Mn(NO3)2; HPV; LiP; ALDHs; THF; FeS; R. jostii; P. putida; GSH; OL; HPLC; Biodegradation; KL; KOH; TCA cycle; HPVZ; PHAs; NAD; PAHs; vdh; ATP; ABTS
• ISSN: 1364-0321; 1879-0690
• DOI: 10.1016/j.rser.2019.03.008

Lignin is the most abundant aromatic polymer in nature. Due to its high amount of phenolic compounds storage, lignin is considered as an alternative source for various polymers and biomaterials production. Except for the native lignin in lignocellulose, a massive amount of technical lignin is being produced daily all over the world. However, the complex structure and low reactivity of lignin limit its further applications and currently, most of the lignin is burned for generating energy. Therefore, the depolymerization of lignin is considered one of the important challenges in lignin utilization. Methods for lignin depolymerization can be divided into thermochemical treatment, mechanical treatment, chemical catalysis, and biological treatment. Different methods for lignin depolymerization, their characteristics and products are extensively discussed in this review. •Various fields of lignin depolymerization methods have been summarized.•Mechanisms, advantages, and disadvantages of each method have been reviewed.•Recent advances in lignin depolymerization have been updated.