Influence of carbon nanotube and ionic liquid on properties of natural rubber nanocomposites

Some properties of carbon nanotube (CNT) filled natural rubber (NR) composites were improved by adding an ionic liquid (IL), 1-butyl-3-methyl imidazolium bis (trifluoromethylsulphonyl)mide (BMI). In this work, the CNT and IL (CNT-IL) were mixed with NR by latex mixing method. Cure characteristics, t...

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Bibliographic Details
Published inExpress polymer letters Vol. 13; no. 4; pp. 327 - 348
Main Authors Krainoi, A., Kummerloewe, C., Nakaramontri, Y., Wisunthorn, S., Vennemann, N., Pichaiyut, S., Kiatkamjornwong, S., Nakason, C.
Format Journal Article
LanguageEnglish
Published Budapest Budapest University of Technology and Economics, Faculty of Mechanical Engineering, Department of Polymer Engineering 01.04.2019
Budapest University of Technology
Subjects
Activated carbon
Carbon nanotubes
electrical conductivity
Electrical resistivity
Engineering
Fourier transforms
Investigations
Ionic liquid
Ionic liquids
Ions
Latex
Mechanical properties
Nanocomposites
Natural rubber
Percolation
Polymers
Rubber
Stress relaxation
Sulfur
Thermal stability
Thermomechanical properties
Vulcanization
Zinc oxides
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Summary:Some properties of carbon nanotube (CNT) filled natural rubber (NR) composites were improved by adding an ionic liquid (IL), 1-butyl-3-methyl imidazolium bis (trifluoromethylsulphonyl)mide (BMI). In this work, the CNT and IL (CNT-IL) were mixed with NR by latex mixing method. Cure characteristics, thermo-mechanical properties, Payne effect, electrical conductivity and thermal stability were investigated. It was found that IL (BMI) accelerated vulcanization reactions and reduced scorch time. In addition, Fourier Transform Infrared (FTIR) results confirmed the role of IL in NR composites along with the reaction between CNT and NR molecules. The temperature scanning stress relaxation (TSSR) measurement was used to assess thermo-mechanical properties, and a relaxation peak of IL was found due to interactions of cations and anions in IL (BMI). Furthermore, the Payne effect was used to qualitatively analyze the roles of IL and CNT in three-dimensional CNT networks in the NR matrix. It was found that CNT dispersion was finer in the NR/CNT composites with IL. Furthermore, the NR/CNT-IL composite had higher electrical conductivity and lower percolation threshold concentration than the NR/CNT composite.
ISSN:1788-618X
1788-618X
DOI:10.3144/expresspolymlett.2019.28