Regularities of Changes in the Structure of Different Phases of Deformed Zirconium Alloys as a Result of Raising the Annealing Temperature According to Texture Analysis Data

• Published in: Metals (Basel ) Vol. 13; no. 10; p. 1784
• Main Authors: Isaenkova, Margarita, Krymskaya, Olga, Klyukova, Kristina, Bogomolova, Anastasya, Kozlov, Ilya, Dzhumaev, Pavel, Fesenko, Vladimir, Svetogorov, Roman
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 01.10.2023
• Subjects: Alloys; Annealing; crystallographic texture; Crystallography; Deformation; Diffraction patterns; electron microscopy; High temperature; Intermetallic compounds; Iron; Laves phase; Microscopy; Niobium base alloys; Phase transitions; Plastic deformation; Polygonization; Qualitative analysis; Radiation; Recrystallization; Sensors; Software; Solid solutions; Specialty metals industry; Synchrotron radiation; Synchrotrons; Texture; Titanium alloys; Tubes; Zirconium; Zirconium alloys; Zirconium base alloys; Germany; Russia
• ISSN: 2075-4701; 2075-4701
• DOI: 10.3390/met13101784

Based on the data of synchrotron and electron microscopic studies of deformed and annealed Russian zirconium alloys, the possibility of analyzing the structural-phase state and crystallographic texture of individual phases has been demonstrated. A qualitative and quantitative phase analysis of deformed and annealed tubes made of Zr-Nb-(Sn-Fe-O) alloys was carried out using diffraction patterns obtained with synchrotron radiation. The main α-Zr phase and the following additional phases: β-Nb, β-Zr, and the Laves phase (intermetallic compound Zr(Nb,Fe)2), were found in the alloys. According to the results of texture analysis of all phases present in the alloy, the mechanisms of plastic deformation, recrystallization, and phase transformations of the main and additional phases were established. It is shown that during plastic deformation of the Zr-1%Nb alloy, a dynamic phase transformation β-Nb→α-Zr→β-Zr is observed. It is established that during recrystallization, larger grains of α-Zr are misoriented relative to the deformed matrix by rotating the prismatic axes around the basal axes by 30°, while fine grains are improved by polygonization and maintain the orientation of the deformed matrix. Processes for changing the orientation of grains of additional phases as a result of high-temperature annealing are also considered.