Phase-field simulation of 2-D Ostwald ripening in the high volume fraction regime

The microstructural evolution and kinetics of Ostwald ripening were studied in the high volume fraction regime by numerically solving the time-dependent Ginzburg–Landau (TDGL) and Cahn–Hilliard equations. It is shown that the growth exponent m is equal to 3, independent of the volume fraction, and t...

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Bibliographic Details
Published inActa materialia Vol. 50; no. 8; pp. 1895 - 1907
Main Authors Fan, Danan, Chen, S.P., Chen, Long-Qing, Voorhees, P.W.
Format Journal Article
LanguageEnglish
Published Oxford Elsevier Ltd 08.05.2002
Elsevier Science
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Summary:The microstructural evolution and kinetics of Ostwald ripening were studied in the high volume fraction regime by numerically solving the time-dependent Ginzburg–Landau (TDGL) and Cahn–Hilliard equations. It is shown that the growth exponent m is equal to 3, independent of the volume fraction, and the kinetic coefficient k increases as the volume fraction increases. The shape of size distributions changes significantly with increasing volume fraction of the coarsening phase; the skewness changes continuously from negative to positive while the kurtosis decreases in the low fraction regime and increases in the high volume fraction regime.
ISSN:1359-6454
1873-2453
DOI:10.1016/S1359-6454(01)00393-7