SELECTIVE SYNTHESIS OF UNSYMMETRICAL DIALKOXYPHOSPHORUS(V)TETRAPHENYLPORPHINE DERIVATIVES BY STEPWISE SUBSTITUTION OF AXIAL POSITION

Unsymmetrical dialkoxyP(V)TPPs are synthesized by treatment of dichloroP(V)TPP with silver nitrate in appropriate alcohols and successive treatment with alkylating reagents under mild conditions at room temperature.

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Bibliographic Details
Published inTetrahedron letters Vol. 33; no. 42; pp. 6327 - 6330
Main Authors KUNIMOTO, K, SEGAWA, H, SHIMIDZU, T
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier 13.10.1992
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
UNSYMMETRICAL SUBSTITUTION
PHOSPHORUS COMPLEXES
PHOSPHORUS(V)PORPHYRIN
HYBRIDIZED MOLECULAR SYSTEM
PORPHYRINS
STEPWISE ALKOXYLATION
O-ALKYLATION
METALLOPORPHYRINS
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Summary:Unsymmetrical dialkoxyP(V)TPPs are synthesized by treatment of dichloroP(V)TPP with silver nitrate in appropriate alcohols and successive treatment with alkylating reagents under mild conditions at room temperature.
ISSN:0040-4039
DOI:10.1016/S0040-4039(00)60965-6