Investigation of surfactant effect on the bubble shape and mass transfer in a milli-channel using high-resolution microfocus X-ray imaging

• Published in: International journal of multiphase flow Vol. 87; pp. 184 - 196
• Main Authors: Haghnegahdar, Mohammadreza, Boden, Stephan, Hampel, Uwe
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.12.2016
• Subjects: Carbon dioxide; Film thickness; Mass transfer; Milli-channels; Surfactant; Taylor bubble; Milli-channels; Surfactant; Film thickness; Taylor bubble; Mass transfer; Carbon dioxide
• ISSN: 0301-9322; 1879-3533
• DOI: 10.1016/j.ijmultiphaseflow.2016.09.010

•X-ray imaging was used to study the effect of surfactant on the mass transfer of bubbles.•Surfactants have a more significant impact on the dissolution rate of small bubbles.•The surfactant effect on the liquid film thickness in small channels was studied.•The liquid film thickening effect of surfactants was measured. In this paper we present an experimental study on the influence of surface active agents (surfactants) on Taylor bubble flow in a vertical millimeter-size channel. Moreover we give a short review on the subject and previous investigations. We investigated the shape and dissolution rate of individual elongated carbon dioxide Taylor bubbles, which were hydraulically fixed in a downward flow of water. Bubble shape and dissolution rate was determined from microfocus X-ray radiographs. From the shrinking rate we calculated the liquid side mass transfer coefficient. The results show that the presence of surfactants causes a change of the bubble shape and leads to a slight increase of the liquid film thickness around the bubble and as a result the elongation of contaminated bubbles. In addition, the comparison of clean and contaminated bubbles indicate that presence of surfactant has a more significant impact on the dissolution rate of small bubbles. Furthermore, applying different concentrations of surfactant reveals that in our case, where surface coverage ratio of surfactant on the bubbles is high, increase of contamination does not have a noticeable influence on the mass transfer coefficient of bubbles.