Effects of Difluoro(oxalato)borate-Based Ionic Liquid as Electrolyte Additive for Li-Ion Batteries
In this work, the use of -methyl- -propylpiperidinium difluoro(oxalato)borate Pip DFOB ionic liquid (IL), originally synthesized in our laboratory, as an additive for liquid electrolytes in lithium-ion batteries (LIBs), is proposed. The synthesized IL exhibits glass and melting transitions at -70.9...
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Published in | Materials Vol. 16; no. 4; p. 1411 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
Switzerland
MDPI AG
08.02.2023
MDPI |
Subjects | |
Online Access | Get full text |
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Summary: | In this work, the use of
-methyl-
-propylpiperidinium difluoro(oxalato)borate Pip
DFOB ionic liquid (IL), originally synthesized in our laboratory, as an additive for liquid electrolytes in lithium-ion batteries (LIBs), is proposed. The synthesized IL exhibits glass and melting transitions at -70.9 °C and 17.1 °C, respectively, and a thermal decomposition temperature over 230 °C. A mixture based on 1.0 M LiPF
in 1:1
/
ethylene carbonate (EC): dimethyl carbonate (DMC) electrolyte solution (so called LP30) and the IL was prepared and tested in lithium metal cells versus two different commercially available carbonaceous electrodes, i.e., graphite (KS6) and graphene (GnP), and versus a high voltage LiNi
Mn
O
(LNMO) cathode. A noticeable improvement was observed for Li|LNMO cells with an IL-added electrolyte, which exhibited a high specific capacity above 120 mAh g
with a Coulombic efficiency above 93% throughout 200 cycles, while the efficiency fell below 80% after 80 cycles with the absence of IL. The results confirm that the IL is promising additive for the electrolyte, especially for a longer cycle life of high-voltage cells. |
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Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 1996-1944 1996-1944 |
DOI: | 10.3390/ma16041411 |