Facile synthesis of cobalt ferrite nanotubes using bacterial nanocellulose as template

• Published in: Carbohydrate polymers Vol. 137; pp. 726 - 731
• Main Authors: Menchaca-Nal, S., Londoño-Calderón, C.L., Cerrutti, P., Foresti, M.L., Pampillo, L., Bilovol, V., Candal, R., Martínez-García, R.
• Format: Journal Article
• Language: English
• Published: England Elsevier Ltd 10.02.2016
• Subjects: Bacteria - chemistry; Bacterial nanocellulose; Biotemplate; Cellulose - chemistry; Cobalt - chemistry; Cobalt ferrite; Combinatorial Chemistry Techniques - methods; Ferric Compounds - chemistry; Microscopy, Electron, Scanning; Nanoparticles - chemistry; Nanotubes; X-Ray Diffraction; Bacterial nanocellulose; Biotemplate; Cobalt ferrite; Nanotubes
• ISSN: 0144-8617; 1879-1344
• DOI: 10.1016/j.carbpol.2015.10.068

•CoFe2O4 nanotubes were synthesized by coprecipitation using BNC as a template.•217 nm-diameter-nanotubes (average) are formed by 9–15nm nanoparticle clusters.•The biotemplated nanotubes have magnetic behavior at room temperature.•A fraction of nanoparticles is in the superparamagnetic state.•Nanoparticles’ crystalline disorder is mainly due to the small crystallite size. A facile method for the preparation of cobalt ferrite nanotubes by use of bacterial cellulose nanoribbons as a template is described. The proposed method relays on a simple coprecipitation operation, which is a technique extensively used for the synthesis of nanoparticles (either isolated or as aggregates) but not for the synthesis of nanotubes. The precursors employed in the synthesis are chlorides, and the procedure is carried out at low temperature (90°C). By the method proposed a homogeneous distribution of cobalt ferrite nanotubes with an average diameter of 217nm in the bacterial nanocellulose (BC) aerogel (3%) was obtained. The obtained nanotubes are formed by 26–102nm cobalt ferrite clusters of cobalt ferrite nanoparticles with diameters in the 9–13nm interval. The nanoparticles that form the nanotubes showed to have a certain crystalline disorder, which could be attributed in a greater extent to the small crystallite size, and, in a lesser extent, to microstrains existing in the crystalline lattice. The BC-templated-CoFe2O4 nanotubes exhibited magnetic behavior at room temperature. The magnetic properties showed to be influenced by a fraction of nanoparticles in superparamagnetic state.