CATALYTIC ASYMMETRIC OXIDATION OF SULFIDES TO SULFOXIDES USING R-(+)-BINAPHTHOL

An asymmetric oxidation system using R-(+)-binaphthol as a chiral auxiliary catalyzes the oxidation of sulfides to chiral sulfoxides in good enantiomeric excess (up to 73% e.e.) and in a high chemical yield.

Saved in:
Bibliographic Details
Published inTetrahedron letters Vol. 33; no. 37; pp. 5391 - 5394
Main Authors KOMATSU, N, NISHIBAYASHI, Y, SUGITA, T, UEMURA, S
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier 08.09.1992
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
CHIRAL TITANIUM COMPLEXES
PRACTICAL ACCESS
ETHERS
ORGANO-ALUMINUM REAGENT
DIELS-ALDER REACTIONS
ALPHA-HYDROXY ESTERS
ALDEHYDES
LEWIS-ACIDS
HIGH ENANTIOMERIC PURITIES
GLYOXYLATE ENE REACTION
Online AccessGet more information

Cover

More Information
Summary:An asymmetric oxidation system using R-(+)-binaphthol as a chiral auxiliary catalyzes the oxidation of sulfides to chiral sulfoxides in good enantiomeric excess (up to 73% e.e.) and in a high chemical yield.
ISSN:0040-4039
DOI:10.1016/S0040-4039(00)79102-7