THE INTRAMOLECULAR SILYL MODIFIED SAKURAI (ISMS) REACTION - A NOVEL AND HIGHLY CONVERGENT SYNTHESIS OF OXOCENES

By employing the intramolecular version of the SMS reaction, oxocenes, including spiroethers and spiroketals, can be prepared in a highly convergent, one-step operation.

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Bibliographic Details
Published inTetrahedron letters Vol. 32; no. 36; pp. 4783 - 4786
Main Authors MEKHALFIA, A, MARKO, IE, ADAMS, H
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier 1991
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
CARBONYL-COMPOUNDS
CONDENSATION
ALLYLSILANES
TETRAHYDROPYRANS
CYCLIZATION
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Summary:By employing the intramolecular version of the SMS reaction, oxocenes, including spiroethers and spiroketals, can be prepared in a highly convergent, one-step operation.
ISSN:0040-4039
DOI:10.1016/S0040-4039(00)92307-4