Hybrid Photoelectrocatalytic TiO2-Co3O4/Co(OH)2 Materials Prepared from Bio-Based Surfactants for Water Splitting

• Published in: Molecules (Basel, Switzerland) Vol. 28; no. 22; p. 7599
• Main Authors: Duquet, Fanny, Flaud, Valérie, Villeneuve-Faure, Christina, Rivallin, Matthieu, Rouessac, Florence, Roualdès, Stéphanie
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 01.11.2023; MDPI
• Subjects: Chemical Sciences; Cobalt; cobalt oxides; Composite materials; Electrons; heterojunctions; Hydrogen; Hydrogen production; Inorganic chemistry; Material chemistry; Organic chemicals; photoanodes; Pore size; Surfactants; Thin films; titanium oxides; water splitting; cobalt oxides; water splitting; heterojunctions; photoanodes; titanium oxides; composite materials
• ISSN: 1420-3049; 1420-3049
• DOI: 10.3390/molecules28227599

The development of new photoanode materials for hydrogen production and water treatment is in full progress. In this context, hybrid TiO2-Co3O4/Co(OH)2 photoanodes prepared using the sol–gel method using biosurfactants are currently being developed by our group. The combination of TiO2 with a cobalt-based compound significantly enhances the visible absorption and electrochemical performance of thin films, which is mainly due to an increase in the specific surface area and a decrease in the charge transfer resistance on the surface of the thin films. The formation of these composites allows for a 30-fold increase in the current density when compared to cobalt-free materials, with the best TiO2-CoN0.5 sample achieving a current of 1.570 mA.cm−2 and a theoretical H2 production rate of 0.3 µmol.min−1.cm−2 under xenon illumination.