Microwave-assisted Kornblum oxidation of organic halides

Microwave-assisted Kornblum oxidation is proved to be an effective way to obtain aldehyde and ketones from their corresponding chlorides. Under microwave irradiation, not only the reaction time was greatly decreased, due to avoiding the by-product, the yield was increased. It is noteworthy that the...

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Bibliographic Details
Published inChinese chemical letters Vol. 18; no. 6; pp. 643 - 646
Main Authors Xu, Gang, Wu, Jian Ping, Ai, Xin Miao, Yang, Li Rong
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.06.2007
College of Material Science and Chemical Engineering, Zhejiang University, Hangzhou 310027, PR China
Subjects
Aldehyde
Halide
Ketones
Kornblum oxidation
Microwave-assisted
Halide
Microwave-assisted
Kornblum oxidation
Ketones
Aldehyde
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Summary:Microwave-assisted Kornblum oxidation is proved to be an effective way to obtain aldehyde and ketones from their corresponding chlorides. Under microwave irradiation, not only the reaction time was greatly decreased, due to avoiding the by-product, the yield was increased. It is noteworthy that the scope of the method was broadly expanded.
ISSN:1001-8417
1878-5964
DOI:10.1016/j.cclet.2007.04.003