Consolidation and properties of binderless sub-micron tungsten carbide by field-activated sintering

• Published in: International journal of refractory metals & hard materials Vol. 22; no. 6; pp. 257 - 264
• Main Authors: Kim, Hwan-Cheol, Shon, In-Jin, Garay, J.E., Munir, Z.A.
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.11.2004
• Subjects: Binderless WC; Densification; Fracture Toughness; Grain size; Hard materials; Hardness; Rapid sintering; SPS; Grain size; Densification; Rapid sintering; SPS; Hard materials; Fracture Toughness; Binderless WC; Hardness
• ISSN: 0263-4368; 2213-3917
• DOI: 10.1016/j.ijrmhm.2004.08.003

The rapid sintering of nano-structured WC hard materials in a short time is introduced with a focus on the manufacturing potential of this spark plasma sintering process. The advantage of this process allows very quick densification to near theoretical density and prohibition of grain growth in nano-structured materials. A dense pure WC hard material with a relative density of up to 97.6% was produced with simultaneous application of 60 MPa pressure and electric current of 2800 A within 2 min. A larger current caused a higher rate of temperature increase and therefore a higher densification rate of the WC powder. The finer the initial WC powder size the higher is the density and the better are the mechanical properties. The fracture toughness and hardness values obtained were 6.6 MPa m 1/2 and 2480 kg/mm 2, respectively under 60 MPa pressure and 2800 A using 0.4 μm WC powder.