Skin and bubble formation in films made of methyl nanocellulose, hydrophobically modified ethyl(hydroxyethyl)cellulose and microfibrillated cellulose

The use of nanomaterials and polymers from renewable resources is important in the search for sustainable alternatives to plastic-based packaging materials and films. In this work, self-supporting thin films prepared from derivatized and non-derivatized nanocellulose and cellulose derivatives were s...

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Published inCellulose (London) Vol. 28; no. 2; pp. 787 - 797
Main Authors Lyytikäinen, Johanna, Morits, Maria, Österberg, Monika, Heiskanen, Isto, Backfolk, Kaj
Format Journal Article
LanguageEnglish
Published Dordrecht Springer Netherlands 2021
Springer Nature B.V
Subjects
Air bubbles
Bioorganic Chemistry
Cellulose
Ceramics
Chemistry
Chemistry and Materials Science
Composites
Composition
Drying
Glass
Homogeneity
Nanomaterials
Natural Materials
Organic Chemistry
Original Research
Physical Chemistry
Polymer Sciences
Properties (attributes)
Renewable resources
Sustainable Development
Temperature effects
Thin films
Viscosity measurement
Hydrophobically modified ethyl(hydroxyethyl)cellulose
Barrier
MFC
Methyl nanocellulose
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Summary:The use of nanomaterials and polymers from renewable resources is important in the search for sustainable alternatives to plastic-based packaging materials and films. In this work, self-supporting thin films prepared from derivatized and non-derivatized nanocellulose and cellulose derivatives were studied. The effect of drying temperature on the film-forming behavior of compositions comprising hydrophobically modified ethyl(hydroxyethyl)cellulose (EHEC), native microfibrillated cellulose (MFC) and nanocellulose made from methyl cellulose was determined. The interaction between the components was assessed from viscosity measurements made at different temperatures, the result being linked to a thermal-dependent association during liquid evaporation, and the subsequent barrier and film-forming properties. The effect of temperature on suspensions was clearly different between the materials, confirming that there were differences in interaction and association between EHEC–MFC and methyl nanocellulose–MFC compositions. The amphiphilic EHEC affected both the suspension homogeneity and the film properties. Air bubbles were formed under certain conditions and composition particularly in MFC films, dependent on the drying procedure. The presence of air bubbles did not affect the oxygen transmission rate or the oil and grease resistance. An increasing amount of MFC improved the oxygen barrier properties of the films.
ISSN:0969-0239
1572-882X
DOI:10.1007/s10570-020-03557-0