Design of novel nano-sorbents based on nano-magnetic iron oxide–bound-nano-silicon oxide–immobilized-triethylenetetramine for implementation in water treatment of heavy metals

• Published in: Chemical engineering journal (Lausanne, Switzerland : 1996) Vol. 223; pp. 318 - 327
• Main Authors: Mahmoud, Mohamed E., Abdelwahab, Mohamed S., Fathallah, Eiman M.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.05.2013
• Subjects: Functionalization; Heavy metals; Nano-Fe3O4; Nano-SiO2; Sorption; Sorption; Functionalization; Nano-Fe3O4; Nano-SiO2; Heavy metals
• ISSN: 1385-8947; 1873-3212
• DOI: 10.1016/j.cej.2013.02.097

A novel nano-sorbent (Nano-Fe3O4–SiO2–TETA) was designed for implementation in water treatment and this sorbent was produced by the direct surface impregnation of magnetic nano-iron oxide with nano-silicon oxide followed by covalent surface binding and immobilization of triethylenetetramine. [Display omitted] • A novel nano-sorbent was designed. • Magnetic nano-iron oxide–nano-silicon oxide-triethylenetetramine sorbent. • Comparison of the metal sorption properties was reported. • Evaluation of the selectivity for some heavy metals. • Implementation in water treatment. Novel nano-sorbents were synthesized from the direct surface impregnation of magnetic nano-iron oxide (Nano-Fe3O4) with nano-silicon oxide (Nano-SiO2) for the formation of (Nano-Fe3O4–SiO2) sorbent. The product material was further functionalized with target nitrogen donor atoms via covalent surface binding and immobilization of triethylenetetramine (TETA) for the formation of (Nano-Fe3O4–SiO2–TETA) sorbent. Functionalized magnetic nano-sorbents were collected by facile separation under the influence of an external magnetic field. The magnetic nano-sorbents were identified by using FT-IR, SEM technique and TGA. The average particle size was found in the range of 14–40nm based on the SEM analysis. All synthesized nano-sorbents were examined to evaluate their selectivity and efficiency in removal of some heavy metal ions such as Cu(II) and Pb(II) from water samples by the batch equilibrium and micro-column techniques. (Nano-Fe3O4–SiO2–TETA) sorbent was identified by a high Cu(II) sorption capacity (480μmolg−1) in pH 7.0, while (Nano-Fe3O4) and (Nano-Fe3O4–SiO2) sorbents were characterized by high affinity to Pb(II). The contributions of various controlling factors such as solution pH, contact time and sorbent dosage on the extraction and sorption processes of metal ions were also studied and optimized.