Formation of Two-Dimensional Supramolecular Icelike Layer Containing (H2O)12 Rings

Water rings: Two novel water chains and layers have been observed in supramolecular solid states. The structures can be interconverted by varying crystallization conditions. The water layer consisting of fused (H2O)12 rings (see structure, O red, H blue) resembles ice Ih.

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Bibliographic Details
Published inAngewandte Chemie International Edition Vol. 43; no. 11; pp. 1374 - 1376
Main Authors Ma, Bao-Qing, Sun, Hao-Ling, Gao, Song
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 05.03.2004
WILEY‐VCH Verlag
Subjects
hydrogen bonds
N ligands
supramolecular chemistry
water
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Summary:Water rings: Two novel water chains and layers have been observed in supramolecular solid states. The structures can be interconverted by varying crystallization conditions. The water layer consisting of fused (H2O)12 rings (see structure, O red, H blue) resembles ice Ih.
Bibliography:This work was supported by the National Science Fund for Distinguished Young Scholars (20125104), NSFC No. 20221101, and the Research Fund for the Doctoral Program of Higher Education (20010001020).
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ArticleID:ANIE200353097
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200353097