Rh- and Pt-catalyzed cycloisomerization of enynes derived from terpenes

The Rh‐catalyzed cycloisomerization of new terpenoid derivatives featuring an O‐tethered enyne unexpectedly leads to polycyclic derivatives containing an inner cyclopropane ring or a diene moiety, depending on the structure of the enyne, as observed in the PtCl2‐catalyzed processes. Copyright © 2008...

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Published inApplied organometallic chemistry Vol. 22; no. 4; pp. 211 - 214
Main Authors Costes, Philippe, Weckesser, Jochen, Dechy-Cabaret, Odile, Urrutigoïty, Martine, Kalck, Philippe
Format Journal Article
LanguageEnglish
Published Chichester, UK John Wiley & Sons, Ltd 01.04.2008
Subjects
enyne cycloisomerization
homogeneous catalysis
platinum
rhodium
terpenes
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Summary:The Rh‐catalyzed cycloisomerization of new terpenoid derivatives featuring an O‐tethered enyne unexpectedly leads to polycyclic derivatives containing an inner cyclopropane ring or a diene moiety, depending on the structure of the enyne, as observed in the PtCl2‐catalyzed processes. Copyright © 2008 John Wiley & Sons, Ltd. The Rh‐catalyzed cycloisomerization of new terpenoids derivatives featuring an O‐tethered enyne unexpectedly leads to polycyclic derivatives containing an inner cyclopropane ring or a diene moiety, depending on the structure of the enyne, as observed in the PtCl2‐catalyzed processes.
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content type line 23
ISSN:0268-2605
1099-0739
DOI:10.1002/aoc.1372