Electronic properties of gold trichloride-graphite intercalation compounds (AuCl 3-GICs)

AuCl 3-intercalated graphite has a significantly short c-axis repeat distance among acceptor-intercalated graphites due to a planar structure of AuCl 3 intercalates. The very high c-axis conductivity σ rt = 23(Ω cm) -1 and the estimated Fermi energy E F = -0.97eV of stage-1 compound suggest strong i...

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Bibliographic Details
Published inSolid state communications Vol. 84; no. 11; pp. 1055 - 1059
Main Authors Ishii, Tomohiko, Nakao, Masato, Suzuki, Kazuya, Enoki, Toshiaki, Nishitani, Ryusuke, Nishina, Yuichiro
Format Journal Article
LanguageEnglish
Published Oxford Elsevier Ltd 01.12.1992
Elsevier
Subjects
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Conductivity of specific materials
Electronic transport in condensed matter
Exact sciences and technology
Physics
Intercalation compound
Electronic properties
Electrical conductivity
Fermi level
Graphite
Strong interaction
Experimental study
Carbon
Gold Chlorides
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Summary:AuCl 3-intercalated graphite has a significantly short c-axis repeat distance among acceptor-intercalated graphites due to a planar structure of AuCl 3 intercalates. The very high c-axis conductivity σ rt = 23(Ω cm) -1 and the estimated Fermi energy E F = -0.97eV of stage-1 compound suggest strong interactions between the graphitic π-system and the AuCl 3 intercalate electrons.
ISSN:0038-1098
1879-2766
DOI:10.1016/0038-1098(92)90439-G