Palladium-catalyzed coupling of organic halides and tertiary allylic amines

The palladium-catalyzed reaction between aryl or perfluoro-alkyl iodides and tertiary allylic amines provides a practical route to 3-aryl- or 3-perfluoroalkyl-allylic amines. The outcome of the arylation of tertiary allylic amines can be affected by a change of solvent. Graphic

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Bibliographic Details
Published inTetrahedron letters Vol. 34; no. 10; pp. 1643 - 1646
Main Authors Filippini, Lucio, Gusmeroli, Marilena, Riva, Raul
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 05.03.1993
Elsevier
Subjects
Chemistry
Chemistry, Organic
Exact sciences and technology
Heck reaction
Organic chemistry
palladium catalysis
perfluoroalkyl iodide
phenyl iodide
Physical Sciences
radical addition
Science & Technology
perfluoroalkyl iodide
Heck reaction
palladium catalysis
radical addition
phenyl iodide
ALCOHOLS
RADICAL ADDITION
PERFLUOROALKYL IODIDE
PALLADIUM CATALYSIS
PHENYL IODIDE
HECK REACTION
Five membered ring
Catalytic reaction
Aliphatic compound
Organic perhalocompound
Nitrogen heterocycle
Tertiary amine
Iodocarbon
Halocarbon
Allylic compound
Chemical coupling
Oxygen nitrogen heterocycle
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Summary:The palladium-catalyzed reaction between aryl or perfluoro-alkyl iodides and tertiary allylic amines provides a practical route to 3-aryl- or 3-perfluoroalkyl-allylic amines. The outcome of the arylation of tertiary allylic amines can be affected by a change of solvent. Graphic
ISSN:0040-4039
1873-3581
DOI:10.1016/0040-4039(93)85030-Z