Tailoring a facile electronic and ionic pathway to boost the storage performance of Fe3O4 nanowires as negative electrode for supercapacitor application

• Published in: Scientific reports Vol. 14; no. 1; pp. 16807 - 14
• Main Authors: Abdelrahim, Ahmed M., El-Moghny, Muhammad G. Abd, Abdelhady, Hosam H., Wali, Hager S., Gamil, Mariam M., Fahmy, Samanta R., Abdel-Hamid, Toka M., Mohammed, Gehad K., Ahmed, Yasmeen A., El-Deab, Mohamed S.
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 22.07.2024; Nature Publishing Group; Nature Portfolio
• Subjects: 639/638/161; 639/638/675; Conductivity; Electrodes; Energy loss; Fe3O4; Graphite felt; Humanities and Social Sciences; Iron oxides; multidisciplinary; Nanotechnology; Nanowires; Negative electrode; Science; Science (multidisciplinary); Specific capacity; Supercapacitor; Surface fluctuations; Graphite felt; Supercapacitor; Negative electrode; Surface fluctuations; Fe; O
• ISSN: 2045-2322; 2045-2322
• DOI: 10.1038/s41598-024-66480-5

Today, high-energy applications are devoted to boosting the storage performance of asymmetric supercapacitors. Importantly, boosting the storage performance of the negative electrodes is a crucial topic. Fe 3 O 4 -based active materials display a promising theoretical storage performance as a negative electrode. Thus, to get a high storage performance of Fe 3 O 4 , it must be tailored to have a higher ionic and electronic conductivity and outstanding stability. Functionalized graphite felt (GF) is an excellent candidate for tailoring Fe 3 O 4 with a facile ionic and electronic pathway. However, the steps of the functionalization of GF are complex and time-consuming as well as the energy loss during this step. Thus, the in-situ functionalization of the GF surface throughout the synthesis of Fe 3 O 4 active materials is proposed herein. Fe 3 O 4 is electrodeposited at the in-situ functionalized GF surface with the crystalline nanowires-like structure as revealed from the various analyses; SEM, TEM, Mapping EDX, XPS, XRD, wettability test, and Raman analysis. Advantageously, the synthetic approach introduces full homogeneous and uniform coverage of the large surface area of the GF. Thus, Fe 3 O 4 nanowires with high ionic and electronic conductivity are characterized by a higher storage performance. Interestingly, Fe 3 O 4 /GF possesses a high specific capacity of 1418 mC cm −2 at a potential scan rate of 10 mV s −1 and this value retained to 54% at a potential scan rate of 50 mV s −1 at an extended potential window of 1.45 V. Remarkably, the diffusion-controlled reaction is the main contributor of the storage of Fe 3 O 4 /GF electrode as revealed by the mechanistic studies.