Synthesis of 3-Cyano-21-Nitro-N-Confused Porphyrin Derivatives by Isoamyl Nitrite

The 3-cyano-21-nitro-N-confused porphyrin derivatives were synthesised by the nitration reaction of 3-cyano-N-confused-porphyrin with isoamyl nitrite at room temperature in moderate yield. The reaction took placed regioselectively in 21-position carbon of inverted pyrrole of N-confused porphyrins.

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Bibliographic Details
Published inJournal of chemical research Vol. 41; no. 9; pp. 517 - 519
Main Authors Zhang, Shaowei, Fu, Xinliang, Ren, Demin, Li, Xiaofang, Yang, Leilei, Yu, Xianyong
Format Journal Article
LanguageEnglish
Published London, England SAGE Publications 01.09.2017
Science Reviews 2000 Ltd
Sage Publications Ltd
Subjects
Chemical synthesis
Chemistry
Chemistry, Multidisciplinary
Derivatives
Nitration
Physical Sciences
Porphyrins
Science & Technology
isoamyl nitrite
N-confused porphyrin
porphyrin
nitration
2-AZA-21-CARBAPORPHYRIN
NORCORROLE
COMPLEX
FUSED PORPHYRIN
BOVINE SERUM-ALBUMIN
TETRAPHENYLPORPHYRIN
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Summary:The 3-cyano-21-nitro-N-confused porphyrin derivatives were synthesised by the nitration reaction of 3-cyano-N-confused-porphyrin with isoamyl nitrite at room temperature in moderate yield. The reaction took placed regioselectively in 21-position carbon of inverted pyrrole of N-confused porphyrins.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 14
ISSN:1747-5198
2047-6507
DOI:10.3184/174751917X15027989008991