Formation of two-dimensional transition metal oxide nanosheets with nanoparticles as intermediates

• Published in: Nature materials Vol. 18; no. 9; pp. 970 - 976
• Main Authors: Yang, Juan, Zeng, Zhiyuan, Kang, Jun, Betzler, Sophia, Czarnik, Cory, Zhang, Xiaowei, Ophus, Colin, Yu, Chang, Bustillo, Karen, Pan, Ming, Qiu, Jieshan, Wang, Lin-Wang, Zheng, Haimei
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 01.09.2019; Nature Publishing Group; Springer Nature - Nature Publishing Group
• Subjects: 639/301/357/1018; 639/301/930/328/2082; Biomaterials; Chemistry; Chemistry and Materials Science; Cobalt; Cobalt oxides; Condensed Matter Physics; Graphene; Hydroxides; Liquid phases; Materials Science; Nanocrystals; Nanoparticles; Nanosheets; Nanotechnology; Nickel; Optical and Electronic Materials; Physics; Surface energy; Transition metal oxides; Transition metals; Two dimensional materials
• ISSN: 1476-1122; 1476-4660; 1476-4660
• DOI: 10.1038/s41563-019-0415-3

Two-dimensional (2D) materials have attracted significant interest because of their large surface-to-volume ratios and electron confinement. Compared to common 2D materials such as graphene or metal hydroxides, with their intrinsic layered atomic structures, the formation mechanisms of 2D metal oxides with a rocksalt structure are not well understood. Here, we report the formation process for 2D cobalt oxide and cobalt nickel oxide nanosheets, after analysis by in situ liquid-phase transmission electron microscopy. Our observations reveal that three-dimensional (3D) nanoparticles are initially formed from the molecular precursor solution and then transform into 2D nanosheets. Ab initio calculations show that a small nanocrystal is dominated by positive edge energy, but when it grows to a certain size, the negative surface energy becomes dominant, driving the transformation of the 3D nanocrystal into a 2D structure. Uncovering these growth pathways, including the 3D-to-2D transition, provides opportunities for future material design and synthesis in solution. Liquid phase transmission electron microscopy reveals the growth pathway of 2D cobalt oxide and cobalt nickel oxide, in which 3D nanoparticles are formed first and then spread and transform into 2D nanosheets.