Effects of morphology on photocatalytic performance of Zinc oxide nanostructures synthesized by rapid microwave irradiation methods

• Published in: Superlattices and microstructures Vol. 51; no. 4; pp. 512 - 522
• Main Authors: Kajbafvala, Amir, Ghorbani, Hamed, Paravar, Asieh, Samberg, Joshua P., Kajbafvala, Ehsan, Sadrnezhaad, S.K.
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.04.2012
• Subjects: Irradiation; Methylene blue (MB); Microwave synthesis; Microwaves; Morphology; Nanocomposites; Nanomaterials; Nanostructure; Photocatalysis; Photocatalytic performance; Zinc oxide; Zinc oxide nanostructures; Microwave synthesis; Photocatalytic performance; Zinc oxide nanostructures; Methylene blue (MB)
• ISSN: 0749-6036; 1096-3677
• DOI: 10.1016/j.spmi.2012.01.015

[Display omitted] ► In this study, simple and fast microwave assisted routes were used for synthesizing ZnO nanostructures with various morphologies. ► Afterward, photocatalytic performance of the fabricated ZnO powders were studied using methylene blue (MB) photodegradation with UV lamp irradiation. ► We were concluded that the functional efficiency of ZnO with spherical morphology is greater that flower-like ZnO nanostructures. In this study, two different chemical solution methods were used to synthesize Zinc oxide nanostructures via a simple and fast microwave assisted method. Afterwards, the photocatalytic performances of the produced ZnO powders were investigated using methylene blue (MB) photodegradation with UV lamp irradiation. The obtained ZnO nanostructures showed spherical and flower-like morphologies. The average crystallite size of the flower-like and spherical nanostructures were determined to be about 55nm and 28nm, respectively. X-ray diffraction (XRD), scanning electronic microscopy (SEM), Brunauer–Emmett–Teller (BET), room temperature photoluminescence (RT-PL) and UV–vis analysis were used for characterization of the synthesized ZnO powders. Using BET N2-adsorption technique, the specific surface area of the flower-like and spherical ZnO nanostructures were found to be 22.9m2/gr and 98m2/gr, respectively. Both morphologies show similar band gap values. Finally, our results depict that the efficiency of photocatalytic performance in the Zinc oxide nanostructures with spherical morphology is greater than that found in the flower-like Zinc oxide nanostructures as well as bulk ZnO.