Kinetics and thermodynamics of Cd(II) biosorption onto loquat (Eriobotrya japonica) leaves

• Published in: Journal of Saudi Chemical Society Vol. 18; no. 5; pp. 486 - 493
• Main Authors: Awwad, Akl M., Salem, Nidá M.
• Format: Journal Article
• Language: English
• Published: Riyadh, Saudi Arabia Elsevier B.V 01.11.2014; Saudi Chemical Society
• Subjects: Absorption and adsorption; Adsorption isotherms; Biological treatment; Biosorption; Cadmium ions; Cadmium removal; Kinetic; Loquat leaves; Pollutants; Purification; Sewage; Thermodynamic; Water; الامتزاز; الامتصاص; الصرف الصحي; المياه; مياه الصرف الصحي; Adsorption isotherms; Biosorption; Cadmium ions; Loquat leaves; Kinetic; Thermodynamic
• ISSN: 1319-6103
• DOI: 10.1016/j.jscs.2011.10.007

A new biosorbent loquat (Eriobotrya japonica) leaves waste for removing cadmium (II) ions from aqueous solutions has been investigated. The extent of biosorption of Cd(II) ions was found to be dependent on solution pH, initial cadmium ion concentrations, biosorbent dose, contact time, and temperature. The experimental equilibrium biosorption data were analyzed by four widely used two-parameters Langmuir, Freundlich, Temkin, and Dubinin–Radushkevich isotherm equations. Langmuir and Temkin isotherm models provided a better fit with the experimental data than Freundlich and Dubinin–Radushkevich isotherm models by high correlation coefficients R2. The thermodynamic analysis indicated that the biosorption behavior of cadmium ions onto loquat leaves (LL) biosorbent was an endothermic process, resulting in higher biosorption capacities at higher temperatures. The negative sign values of ΔG0 and positive values of ΔH0 revealed that the biosorption process was spontaneous and endothermic. Kinetic studies showed that pseudo-second order described the biosorption experimental data better than the pseudo-first order kinetic model. The (LL) were successfully used for the biosorption of cadmium ions from contaminated water sources.