Synthesis, characterization and antimicrobial properties of grafted sugarcane bagasse/silver nanocomposites
•SCB was successfully grafted with acrylamide and glycidyl methacrylate.•The optimum grafting conditions were determined.•The ungrafted, grafted SCB and their Ag nanocomposites were characterized.•The grafted SCB/Ag nanocomposites exhibited better antimicrobial activity than ungrafted SCB/Ag nanocom...
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Published in | Carbohydrate polymers Vol. 115; pp. 276 - 284 |
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Main Authors | , |
Format | Journal Article |
Language | English |
Published |
England
Elsevier Ltd
22.01.2015
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Subjects | |
Online Access | Get full text |
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Summary: | •SCB was successfully grafted with acrylamide and glycidyl methacrylate.•The optimum grafting conditions were determined.•The ungrafted, grafted SCB and their Ag nanocomposites were characterized.•The grafted SCB/Ag nanocomposites exhibited better antimicrobial activity than ungrafted SCB/Ag nanocomposites.
Sugarcane bagasse (SCB) was grafted with acrylamide (AAm) and glycidyl methacrylate (GMA) by chemical oxidation method. The effect of monomer/initiator molar ratio, reaction time, reaction temperature and material to liquor ratio on the degree of grafting was investigated. The optimum conditions for grafting were: monomer/initiator molar ratio 1 for AAm and 2 for GMA, reaction time 4h, reaction temperature 80°C and materials to liquor ratio 1:20. Silver nanoparticles (AgNPs) were prepared and characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). Ungrafted SCB, SCB-g-AAm and SCB-g-GMA were impregnated into silver (Ag) nanoparticles colloidal solution. The ungrafted SCB, grafted SCB and their nanocomposites with Ag nanoparticles were characterized by FT-IR spectroscopy, X-ray diffraction (XRD) and scanning electron microscopy (SEM). The grafted SCB/Ag nanoparticles exhibit better antimicrobial activity against Escherichia coli as the model Gram-negative bacteria, Staphylococcus aureus as the model Gram-positive bacteria and Aspergillus flavus and Candida albicans (yeasts) than ungrafted SCB/AgNPs. |
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Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 0144-8617 1879-1344 |
DOI: | 10.1016/j.carbpol.2014.08.052 |