Palladium-catalysed intramolecular carbenoid insertion of alpha-diazo-alpha-(methoxycarbonyl) acetanilides for oxindole synthesis

A novel, selective palladium-catalysed carbenoid C(aryl)-H insertion of alpha-diazo-alpha-(methoxycarbonyl) acetanilides leading to oxindoles is described.

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 53; no. 21; pp. 3110 - 3113
Main Authors Sole, Daniel, Perez-Janer, Ferran, Fernandez, Israel
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 09.03.2017
Royal Society of Chemistry
Subjects
Carbenes
Carbens
Catalysis
Catàlisi
Chemistry
Chemistry, Multidisciplinary
Insertion
Organic synthesis
Palladium
Pal·ladi (Element químic)
Physical Sciences
Science & Technology
Synthesis
Síntesi orgànica
FUNCTIONALIZATION
ALPHA-DIAZOCARBONYL COMPOUNDS
GOLD
3-ALKYLIDENEOXINDOLES
ALKYLATION
DIAZOAMIDES
DIAZO-COMPOUNDS
SELECTIVITY
C-H BONDS
N-TOSYLHYDRAZONES
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Summary:A novel, selective palladium-catalysed carbenoid C(aryl)-H insertion of alpha-diazo-alpha-(methoxycarbonyl) acetanilides leading to oxindoles is described.
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ISSN:1359-7345
1364-548X
DOI:10.1039/c7cc00718c