High performance electrocatalysts supported on graphene based hybrids for polymer electrolyte membrane fuel cells

• Published in: International journal of hydrogen energy Vol. 43; no. 52; pp. 23221 - 23230
• Main Authors: Yarar Kaplan, Begüm, Haghmoradi, Navid, Biçer, Emre, Merino, César, Alkan Gürsel, Selmiye
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 27.12.2018
• Subjects: Electrocatalyst; Graphene; Hybrid catalyst support; PEM fuel cell; Pt nanoparticle; Hybrid catalyst support; Electrocatalyst; Pt nanoparticle; Graphene; PEM fuel cell
• ISSN: 0360-3199; 1879-3487
• DOI: 10.1016/j.ijhydene.2018.10.222

In this study, new electrocatalysts for PEM fuel cells, based on Pt nanoparticles supported on hybrid carbon support networks comprising reduced graphene oxide (rGO) and carbon black (CB) at varying ratios, were designed and prepared by means of a rapid and efficient microwave-assisted synthesis method. Resultant catalysts were characterized ex-situ for their structure, morphology, electrocatalytic activity. In addition, membrane-electrode assemblies (MEAs) fabricated using resultant electrocatalysts and evaluated in-situ for their fuel cell performance and impedance characteristics. TEM studies showed that Pt nanoparticles were homogeneously decorated on rGO and rGO-CB hybrids while they had bigger size and partially agglomerated distribution on CB. The electrocatalyst, supported on GO-CB hybrid containing 75% GO (HE75), possessed very encouraging results in terms of Pt particle size and dispersion, catalytic activity towards HOR and ORR, and fuel cell performance. The maximum power density of 1090 mW cm−2 was achieved with MEA (Pt loading of 0.4 mg cm−2) based on electrocatalyst, HE75. Therefore, the resultant hybrid demonstrated higher Pt utilization with enhanced FC performance output. Our results, revealing excellent attributes of hybrid supported electrocatalysts, can be ascribed to the role of CB preventing rGO sheets from restacking, effectively modifying the array of graphene and providing more available active catalyst sites in the electrocatalyst material. [Display omitted] •1–2 nm Pt nanoparticles on GO-CB hybrids were achieved by microwave-based synthesis.•Pt nanoparticles, as electrocatalysts, were uniformly decorated on GO-CB hybrids.•Pt nanoparticles supported on GO-CB hybrids exhibited enhanced catalytic activity.•Pt on GO-CB hybrid with 75% GO yielded power density of 1090 mW cm−2 in fuel cells.