Continuous hydrothermal co-liquefaction of aspen wood and glycerol with water phase recirculation

• Published in: Applied energy Vol. 162; pp. 1034 - 1041
• Main Authors: Pedersen, T.H., Grigoras, I.F., Hoffmann, J., Toor, S.S., Daraban, I.M., Jensen, C.U., Iversen, S.B., Madsen, R.B., Glasius, M., Arturi, K.R., Nielsen, R.P., Søgaard, E.G., Rosendahl, L.A.
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 15.01.2016
• Subjects: Biocrude; Biofuel; Biomass; Continuous processing; Hydrothermal liquefaction; Sustainability; Biocrude; Biofuel; Continuous processing; Biomass; Hydrothermal liquefaction; Sustainability
• ISSN: 0306-2619; 1872-9118
• DOI: 10.1016/j.apenergy.2015.10.165

•Biocrude compounds from woody biomass can be classified into two groups: cyclopentenones and oxygenated aromatics.•Biocrude quality can be predicted based on the feedstock model compound composition.•Elemental composition is almost invariant to feedstock composition.•Reaction scheme from model compound, through intermediates, to biocrude is proposed.•Residual oxygen in the biocrude is mainly positioned in ketones and phenolic alcohols. Hydrothermal liquefaction is a promising technology for the conversion of a wide range of bio-feedstock into a biocrude; a mixture of chemical compounds that holds the potential for a renewable production of chemicals and fuels. Most research in hydrothermal liquefaction is performed in batch type reactors, although a continuous and energy-efficient operation is paramount for such process to be feasible. In this work an experimental campaign in a continuous bench scale unit is presented. The campaign is based on glycerol-assisted hydrothermal liquefaction of aspen wood carried out with the presence of a homogeneous catalyst at supercritical water conditions, 400°C and 300bar. Furthermore, in the experimental campaign a water phase recirculation step is incorporated to evaluate the technical feasibility of such procedure. In total, four batches of approximately 100kg of feed each were processed successfully at steady state conditions without any observation of system malfunctioning. The biocrude obtained was characterized using several analytical methods to evaluate the feasibility of the process and the quality of the product. Results showed that a high quality biocrude was obtained having a higher heating value of 34.3MJ/kg. The volatile fraction of the biocrude consisted mostly of compounds having number of carbon atoms in the C6–C12 range similar to gasoline. In terms of process feasibility, it was revealed that total organic carbon (TOC) and ash significantly accumulated in the water phase when such is recirculated for the proceeding batch. After four batches the TOC and the ash mass fraction of the water phase were 136.2 [g/L] and 12.6 [%], respectively. Water phase recirculation showed a slight increase in the biocrude quality in terms on an effective hydrogen-to-carbon ratio, but it showed no effects on the product gas composition or the pH of the water phase. The successful operation demonstrated the technical feasibility of a continuous production of high quality biocrude.