Porous CuO microsphere architectures as high-performance cathode materials for aluminum-ion batteries
Cathode materials with a porous structure are important in the development of aluminum-ion batteries (AIBs). In this research, porous microspheric copper oxide (PM-CuO) composed of stacked numerous bitty nanorods has been synthesized for use in AIBs. Using a simple one-pot hydrothermal process, the-...
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| Published in | Journal of materials chemistry. A, Materials for energy and sustainability Vol. 6; no. 7; pp. 3084 - 3090 |
|---|---|
| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Cambridge
Royal Society of Chemistry
2018
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| Subjects | |
| Online Access | Get full text |
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| Abstract | Cathode materials with a porous structure are important in the development of aluminum-ion batteries (AIBs). In this research, porous microspheric copper oxide (PM-CuO) composed of stacked numerous bitty nanorods has been synthesized for use in AIBs. Using a simple one-pot hydrothermal process, the-as-synthesized PM-CuO possess a large specific surface area of 21.61 m
2
g
−1
and a pore volume of 0.179 cm
3
g
−1
. These unique porous features allow PM-CuO to improve the electrochemical performance in the assembled AIBs, which exhibit a high initial charge and discharge capacity of 270.62 and 250.12 mA h g
−1
(current density of 50 mA g
−1
), respectively. In the cycling performance, discharge capacity was observed to remain over 130, 121 and 112 mA h g
−1
at current densities of 50, 100 and 200 mA g
−1
, respectively. The favorable properties of PM-CuO cathode materials are attributed to the unique porous structure and this makes them a promising potential material for use as energy storage devices. |
|---|---|
| AbstractList | Cathode materials with a porous structure are important in the development of aluminum-ion batteries (AIBs). In this research, porous microspheric copper oxide (PM-CuO) composed of stacked numerous bitty nanorods has been synthesized for use in AIBs. Using a simple one-pot hydrothermal process, the-as-synthesized PM-CuO possess a large specific surface area of 21.61 m² g⁻¹ and a pore volume of 0.179 cm³ g⁻¹. These unique porous features allow PM-CuO to improve the electrochemical performance in the assembled AIBs, which exhibit a high initial charge and discharge capacity of 270.62 and 250.12 mA h g⁻¹ (current density of 50 mA g⁻¹), respectively. In the cycling performance, discharge capacity was observed to remain over 130, 121 and 112 mA h g⁻¹ at current densities of 50, 100 and 200 mA g⁻¹, respectively. The favorable properties of PM-CuO cathode materials are attributed to the unique porous structure and this makes them a promising potential material for use as energy storage devices. Cathode materials with a porous structure are important in the development of aluminum-ion batteries (AIBs). In this research, porous microspheric copper oxide (PM-CuO) composed of stacked numerous bitty nanorods has been synthesized for use in AIBs. Using a simple one-pot hydrothermal process, the-as-synthesized PM-CuO possess a large specific surface area of 21.61 m 2 g −1 and a pore volume of 0.179 cm 3 g −1 . These unique porous features allow PM-CuO to improve the electrochemical performance in the assembled AIBs, which exhibit a high initial charge and discharge capacity of 270.62 and 250.12 mA h g −1 (current density of 50 mA g −1 ), respectively. In the cycling performance, discharge capacity was observed to remain over 130, 121 and 112 mA h g −1 at current densities of 50, 100 and 200 mA g −1 , respectively. The favorable properties of PM-CuO cathode materials are attributed to the unique porous structure and this makes them a promising potential material for use as energy storage devices. Cathode materials with a porous structure are important in the development of aluminum-ion batteries (AIBs). In this research, porous microspheric copper oxide (PM-CuO) composed of stacked numerous bitty nanorods has been synthesized for use in AIBs. Using a simple one-pot hydrothermal process, the-as-synthesized PM-CuO possess a large specific surface area of 21.61 m2 g−1 and a pore volume of 0.179 cm3 g−1. These unique porous features allow PM-CuO to improve the electrochemical performance in the assembled AIBs, which exhibit a high initial charge and discharge capacity of 270.62 and 250.12 mA h g−1 (current density of 50 mA g−1), respectively. In the cycling performance, discharge capacity was observed to remain over 130, 121 and 112 mA h g−1 at current densities of 50, 100 and 200 mA g−1, respectively. The favorable properties of PM-CuO cathode materials are attributed to the unique porous structure and this makes them a promising potential material for use as energy storage devices. |
| Author | Zhang, Guohua Jiao, Shuqiang Li, Shijie Wang, Shuai Zhang, Xuefeng |
| Author_xml | – sequence: 1 givenname: Xuefeng surname: Zhang fullname: Zhang, Xuefeng organization: State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, PR China – sequence: 2 givenname: Guohua surname: Zhang fullname: Zhang, Guohua organization: State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, PR China – sequence: 3 givenname: Shuai surname: Wang fullname: Wang, Shuai organization: State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, PR China – sequence: 4 givenname: Shijie surname: Li fullname: Li, Shijie organization: State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, PR China – sequence: 5 givenname: Shuqiang orcidid: 0000-0001-9600-752X surname: Jiao fullname: Jiao, Shuqiang organization: State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, PR China |
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| Snippet | Cathode materials with a porous structure are important in the development of aluminum-ion batteries (AIBs). In this research, porous microspheric copper oxide... |
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| SubjectTerms | Aluminum Aluminum-ion batteries batteries Cathodes copper Copper oxides cupric oxide Current density Discharge Electrochemical analysis Electrochemistry Electrode materials energy Energy consumption Energy storage Lithium microparticles Nanorods Porous materials surface area Synthesis |
| Title | Porous CuO microsphere architectures as high-performance cathode materials for aluminum-ion batteries |
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