Porous CuO microsphere architectures as high-performance cathode materials for aluminum-ion batteries

• Published in: Journal of materials chemistry. A, Materials for energy and sustainability Vol. 6; no. 7; pp. 3084 - 3090
• Main Authors: Zhang, Xuefeng, Zhang, Guohua, Wang, Shuai, Li, Shijie, Jiao, Shuqiang
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 2018
• Subjects: Aluminum; Aluminum-ion batteries; batteries; Cathodes; copper; Copper oxides; cupric oxide; Current density; Discharge; Electrochemical analysis; Electrochemistry; Electrode materials; energy; Energy consumption; Energy storage; Lithium; microparticles; Nanorods; Porous materials; surface area; Synthesis
• ISSN: 2050-7488; 2050-7496; 2050-7496
• DOI: 10.1039/C7TA10632G

Cathode materials with a porous structure are important in the development of aluminum-ion batteries (AIBs). In this research, porous microspheric copper oxide (PM-CuO) composed of stacked numerous bitty nanorods has been synthesized for use in AIBs. Using a simple one-pot hydrothermal process, the-as-synthesized PM-CuO possess a large specific surface area of 21.61 m 2 g −1 and a pore volume of 0.179 cm 3 g −1 . These unique porous features allow PM-CuO to improve the electrochemical performance in the assembled AIBs, which exhibit a high initial charge and discharge capacity of 270.62 and 250.12 mA h g −1 (current density of 50 mA g −1 ), respectively. In the cycling performance, discharge capacity was observed to remain over 130, 121 and 112 mA h g −1 at current densities of 50, 100 and 200 mA g −1 , respectively. The favorable properties of PM-CuO cathode materials are attributed to the unique porous structure and this makes them a promising potential material for use as energy storage devices.