H-Phosphonate-Mediated Amination of Quinoline N-Oxides with Tertiary Amines: A Mild and Metal-Free Synthesis of 2-Dialkylaminoquinolines
A synthetic strategy has been developed for the synthesis of 2‐dialkylaminoquinolines from easily available quinoline N‐oxides, tertiary amines, diisopropyl H‐phosphonate and carbon tetrachloride (CCl4) in one pot under metal‐free conditions at room temperature.
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| Published in | Advanced synthesis & catalysis Vol. 356; no. 9; pp. 1979 - 1985 |
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| Main Authors | , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Weinheim
WILEY-VCH Verlag
16.06.2014
WILEY‐VCH Verlag Wiley |
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| Abstract | A synthetic strategy has been developed for the synthesis of 2‐dialkylaminoquinolines from easily available quinoline N‐oxides, tertiary amines, diisopropyl H‐phosphonate and carbon tetrachloride (CCl4) in one pot under metal‐free conditions at room temperature. |
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| AbstractList | A synthetic strategy has been developed for the synthesis of 2-dialkylaminoquinolines from easily available quinoline N-oxides, tertiary amines, diisopropyl H-phosphonate and carbon tetrachloride (CCl4) in one pot under metal-free conditions at room temperature. Abstract A synthetic strategy has been developed for the synthesis of 2‐dialkylaminoquinolines from easily available quinoline N ‐oxides, tertiary amines, diisopropyl H‐phosphonate and carbon tetrachloride (CCl 4 ) in one pot under metal‐free conditions at room temperature. magnified image A synthetic strategy has been developed for the synthesis of 2-dialkylaminoquinolines from easily available quinoline N-oxides, tertiary amines, diisopropyl H-phosphonate and carbon tetrachloride (CCl sub(4)) in one pot under metal-free conditions at room temperature. |
| Author | Qu, Lingbo Li, Xu Qu, Zhibo Zhao, Yufen Chen, Jianyu Ke, Diandian Duan, Likun Yuan, Jinwei Chen, Xiaolan Mai, Wenpeng |
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| Keywords | quinoline N-oxides REAGENT 2-dialkylaminoquinolines DIALKYL CHLOROPHOSPHATES DESIGN C-H activation C-N coupling H-phosphonates EFFICIENT DERIVATIVES |
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| Snippet | A synthetic strategy has been developed for the synthesis of 2‐dialkylaminoquinolines from easily available quinoline N‐oxides, tertiary amines, diisopropyl... A synthetic strategy has been developed for the synthesis of 2-dialkylaminoquinolines from easily available quinoline N-oxides, tertiary amines, diisopropyl... Abstract A synthetic strategy has been developed for the synthesis of 2‐dialkylaminoquinolines from easily available quinoline N ‐oxides, tertiary amines,... |
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| StartPage | 1979 |
| SubjectTerms | 2-dialkylaminoquinolines Amines Carbon tetrachloride Catalysis Chemistry Chemistry, Applied Chemistry, Organic CH activation CN coupling H-phosphonates Physical Sciences Quinoline quinoline N-oxides Science & Technology Strategy Synthesis |
| Title | H-Phosphonate-Mediated Amination of Quinoline N-Oxides with Tertiary Amines: A Mild and Metal-Free Synthesis of 2-Dialkylaminoquinolines |
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