Cobalt-Catalyzed Direct Amination of Arenes with Alkylamines via Bidentate-Chelation Assistance

Cobalt‐catalyzed C−H amination of arenes with alkylamines by the assistance of 8‐aminoquinoline as auxiliary through sp2 C−H bond functionalization has been achieved. Attractive features of this protocol include the low loading of the cobalt catalyst and the readily available reagents.

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Bibliographic Details
Published inAdvanced synthesis & catalysis Vol. 358; no. 16; pp. 2707 - 2711
Main Authors Yan, Qiangqiang, Xiao, Tangxin, Liu, Zhanxiang, Zhang, Yuhong
Format Journal Article
LanguageEnglish
Published WEINHEIM Blackwell Publishing Ltd 18.08.2016
Wiley
Subjects
8-aminoquinoline as auxiliary
Alkylamines
Aromatic compounds
Bonding
Catalysis
Catalysts
Chemistry
Chemistry, Applied
Chemistry, Organic
Cobalt
C−H amination
Physical Sciences
Reagents
Science & Technology
Synthesis
CUPRIC ACETATE
C-H amination
ROOM-TEMPERATURE
AZIDES
AMIDATION
TERMINAL ALKYNES
cobalt
DIARYLAMINES
alkylamines
8-aminoquinoline as auxiliary
ARYL
CARBON-NITROGEN BONDS
DERIVATIVES
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Summary:Cobalt‐catalyzed C−H amination of arenes with alkylamines by the assistance of 8‐aminoquinoline as auxiliary through sp2 C−H bond functionalization has been achieved. Attractive features of this protocol include the low loading of the cobalt catalyst and the readily available reagents.
Bibliography:ArticleID:ADSC201600282
ark:/67375/WNG-TDL0VHR7-4
National Basic Research Program of China - No. 2011CB936003
Natural Science Foundation of China - No. 21272205
Program for the Zhejiang Leading Team of Science and Technology Innovation - No. 2011R50007
istex:E7A28AFFA99CD5A1ED386B0C90F67022C726AA28
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.201600282