Effect of laser power on orientation and microstructure of TiO2 films prepared by laser chemical vapor deposition method

• Published in: Materials letters Vol. 93; pp. 179 - 182
• Main Authors: Guo, Dongyun, Ito, Akihiko, Goto, Takashi, Tu, Rong, Wang, Chuanbin, Shen, Qiang, Zhang, Lianmeng
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 15.02.2013
• Subjects: Laser chemical vapor deposition; Laser power; Microstructure; Orientation; temperature; TiO2 film; titanium dioxide; vapors; Orientation; Microstructure; Laser chemical vapor deposition; TiO2 film; Laser power
• ISSN: 0167-577X; 1873-4979
• DOI: 10.1016/j.matlet.2012.11.121

The TiO2 films were prepared on Pt/Ti/SiO2/Si substrate by a laser chemical vapor deposition method. With increasing laser power (PL) from 48 to 98W, the deposition temperature (Tdep) monotonously increased from 849 to 929K. At Tdep=849K (PL=48W), the rutile TiO2 film was prepared with strong (110) and (200) peaks. With increasing Tdep from 849 to 883K (PL=71W), the intensity of (110) peak increased. The (110)-oriented TiO2 films were obtained for Tdep beyond 903K (PL=81W). All TiO2 films showed faceted grains with the columnar cross-section. With increasing Tdep, the grain size increased and the column became wider. The high deposition rate (Rdep) ranged from 13.04 to 24.84μmh−1. ► Rutile TiO2 films were prepared on Pt/Ti/SiO2/Si substrate by laser CVD. ► With increasing laser power, orientation of TiO2 films changed. ► With increasing laser power, microstructure of TiO2 films changed.