Wear resistant epoxy composites with diisocyanate-based self-healing functionality

Hexamethylene diisocyanate (HDI) filled microcapsules were developed and incorporated in epoxy matrices to form a new type of wear resistant epoxy composites. The tribological properties of the epoxy composites were systemically investigated. The friction and wear of the composites slid against a Cr...

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Published inWear Vol. 313; no. 1-2; pp. 19 - 28
Main Authors Khun, N.W., Sun, D.W., Huang, M.X., Yang, J.L., Yue, C.Y.
Format Journal Article
LanguageEnglish
Published Amsterdam Elsevier B.V 15.05.2014
Elsevier
Subjects
Applied sciences
Composites
Exact sciences and technology
Forms of application and semi-finished materials
Friction
HDI filled microcapsule
Hexamethylene diisocyanate
Liquids
Lubrication
Mechanical properties
Physical properties
Polymer
Polymer industry, paints, wood
Polymer matrix composites
Properties and testing
Self-healing
Sliding
Sliding wear
Technology of polymers
Wear
Wear resistance
HDI filled microcapsule
Polymer
Self-healing
Sliding wear
Scanning electron microscopy
Surface morphology
Microcapsule
Epoxy resin
Composite material
Lubricant
Optical microscopy
Wear rate
Organic cyanate
Wear layer
Wear resistance
Ball on disk testing
Self lubricating material
Built in self repair
Sliding friction
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Abstract Hexamethylene diisocyanate (HDI) filled microcapsules were developed and incorporated in epoxy matrices to form a new type of wear resistant epoxy composites. The tribological properties of the epoxy composites were systemically investigated. The friction and wear of the composites slid against a Cr6 steel ball at different sliding speeds under various normal loads decreased with increased microcapsule content because of the lubricating effect of released HDI liquid from ruptured microcapsules during the wear test and the self-healing process of the released HDI liquid with the moisture to form new polyurea layers on the wear track. It can be concluded that the incorporation of microencapsulated HDI liquid is an effective way to lessen the wear of the epoxy composites during sliding via the self-healing process with a concurrent self-lubricating effect of the released HDI liquid. Wear-healing kinetics of epoxy under sliding wear loading condition. [Display omitted] •Study investigates the sliding wear of HDI based self-healing epoxies.•Released liquid HDI slightly lowers friction due to its lubricating effect.•High capsule content greatly reduces wear due to self-healing of released HDI.
AbstractList Hexamethylene diisocyanate (HDI) filled microcapsules were developed and incorporated in epoxy matrices to form a new type of wear resistant epoxy composites. The tribological properties of the epoxy composites were systemically investigated. The friction and wear of the composites slid against a Cr6 steel ball at different sliding speeds under various normal loads decreased with increased microcapsule content because of the lubricating effect of released HDI liquid from ruptured microcapsules during the wear test and the self-healing process of the released HDI liquid with the moisture to form new polyurea layers on the wear track. It can be concluded that the incorporation of microencapsulated HDI liquid is an effective way to lessen the wear of the epoxy composites during sliding via the self-healing process with a concurrent self-lubricating effect of the released HDI liquid.
Hexamethylene diisocyanate (HDI) filled microcapsules were developed and incorporated in epoxy matrices to form a new type of wear resistant epoxy composites. The tribological properties of the epoxy composites were systemically investigated. The friction and wear of the composites slid against a Cr6 steel ball at different sliding speeds under various normal loads decreased with increased microcapsule content because of the lubricating effect of released HDI liquid from ruptured microcapsules during the wear test and the self-healing process of the released HDI liquid with the moisture to form new polyurea layers on the wear track. It can be concluded that the incorporation of microencapsulated HDI liquid is an effective way to lessen the wear of the epoxy composites during sliding via the self-healing process with a concurrent self-lubricating effect of the released HDI liquid. Wear-healing kinetics of epoxy under sliding wear loading condition. [Display omitted] •Study investigates the sliding wear of HDI based self-healing epoxies.•Released liquid HDI slightly lowers friction due to its lubricating effect.•High capsule content greatly reduces wear due to self-healing of released HDI.
Author Huang, M.X.
Khun, N.W.
Yue, C.Y.
Sun, D.W.
Yang, J.L.
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  surname: Yue
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Issue 1-2
Keywords HDI filled microcapsule
Polymer
Self-healing
Sliding wear
Scanning electron microscopy
Surface morphology
Microcapsule
Epoxy resin
Composite material
Lubricant
Optical microscopy
Wear rate
Organic cyanate
Wear layer
Wear resistance
Ball on disk testing
Self lubricating material
Built in self repair
Sliding friction
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Snippet Hexamethylene diisocyanate (HDI) filled microcapsules were developed and incorporated in epoxy matrices to form a new type of wear resistant epoxy composites....
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SubjectTerms Applied sciences
Composites
Exact sciences and technology
Forms of application and semi-finished materials
Friction
HDI filled microcapsule
Hexamethylene diisocyanate
Liquids
Lubrication
Mechanical properties
Physical properties
Polymer
Polymer industry, paints, wood
Polymer matrix composites
Properties and testing
Self-healing
Sliding
Sliding wear
Technology of polymers
Wear
Wear resistance
Title Wear resistant epoxy composites with diisocyanate-based self-healing functionality
URI https://dx.doi.org/10.1016/j.wear.2014.02.011
https://search.proquest.com/docview/1559683671
https://search.proquest.com/docview/1677979857
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