Wear resistant epoxy composites with diisocyanate-based self-healing functionality

• Published in: Wear Vol. 313; no. 1-2; pp. 19 - 28
• Main Authors: Khun, N.W., Sun, D.W., Huang, M.X., Yang, J.L., Yue, C.Y.
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 15.05.2014; Elsevier
• Subjects: Applied sciences; Composites; Exact sciences and technology; Forms of application and semi-finished materials; Friction; HDI filled microcapsule; Hexamethylene diisocyanate; Liquids; Lubrication; Mechanical properties; Physical properties; Polymer; Polymer industry, paints, wood; Polymer matrix composites; Properties and testing; Self-healing; Sliding; Sliding wear; Technology of polymers; Wear; Wear resistance; HDI filled microcapsule; Polymer; Self-healing; Sliding wear; Scanning electron microscopy; Surface morphology; Microcapsule; Epoxy resin; Composite material; Lubricant; Optical microscopy; Wear rate; Organic cyanate; Wear layer; Wear resistance; Ball on disk testing; Self lubricating material; Built in self repair; Sliding friction
• ISSN: 0043-1648; 1873-2577
• DOI: 10.1016/j.wear.2014.02.011

Hexamethylene diisocyanate (HDI) filled microcapsules were developed and incorporated in epoxy matrices to form a new type of wear resistant epoxy composites. The tribological properties of the epoxy composites were systemically investigated. The friction and wear of the composites slid against a Cr6 steel ball at different sliding speeds under various normal loads decreased with increased microcapsule content because of the lubricating effect of released HDI liquid from ruptured microcapsules during the wear test and the self-healing process of the released HDI liquid with the moisture to form new polyurea layers on the wear track. It can be concluded that the incorporation of microencapsulated HDI liquid is an effective way to lessen the wear of the epoxy composites during sliding via the self-healing process with a concurrent self-lubricating effect of the released HDI liquid. Wear-healing kinetics of epoxy under sliding wear loading condition. [Display omitted] •Study investigates the sliding wear of HDI based self-healing epoxies.•Released liquid HDI slightly lowers friction due to its lubricating effect.•High capsule content greatly reduces wear due to self-healing of released HDI.