The effect of M23C6 carbides on the formation of grain boundary serrations in a wrought Ni-based superalloy

• Published in: Materials science & engineering. A, Structural materials : properties, microstructure and processing Vol. 536; pp. 37 - 44
• Main Authors: Jiang, Li, Hu, Rui, Kou, Hongchao, Li, Jinshan, Bai, Guanghai, Fu, Hengzhi
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier B.V 28.02.2012; Elsevier
• Subjects: Cross-disciplinary physics: materials science; rheology; Diffusion; Exact sciences and technology; Grain boundary serrations; Haynes 230 alloy; M23C6; Materials science; Phase diagrams and microstructures developed by solidification and solid-solid phase transformations; Physics; Precipitation; Grain boundary serrations; Haynes 230 alloy; Diffusion; M23C6; Grain boundaries; Nickel base alloys; Scanning electron microscopy; C; Interface energy; Haynes alloys; Electron diffraction; Wrought alloy; M; Solution heat treatment; Precipitation; Transmission electron microscopy; Solid solutions; Microstructure; Serrated yielding; Transition element alloys
• ISSN: 0921-5093; 1873-4936
• DOI: 10.1016/j.msea.2011.11.060

► The characteristics of GBS are dependent on the solution treatment conditions. ► The morphology of M23C6 carbides have a direct influence on the formation of GBS. ► The difference of diffusivity at interfaces cause M23C6 carbides and serrations. The effect of M23C6 carbides on the formation of grain boundary serrations (GBSs) has been systematically investigated in a solid solution strengthened Haynes 230 alloy. It is found that GBS occur in this alloy during the slow cooling process and are accompanied by the precipitation of intergranular planar M23C6 carbides. The amplitude and proportion of GBS increase with the rise of the solution temperature and time. If the specimens are cooled directly without any solution treatments, the grain boundaries remain planar and granular M23C6 carbides precipitate at them. The sequential evolutions of GBS and M23C6 carbides are investigated by scanning electron microscopy (SEM) examination. High-resolution transmission electron microscope (HRTEM) investigations reveal the coherent interfacial plane of M23C6 carbides formed at grain boundaries to be (1 1 1¯). These facts indicate that the nucleation and oriented growth of M23C6 carbides at grain boundaries play an important role in the formation of GBS. Based on the interfacial energy calculations and the tensions balance relation, a semi-quantitative model about the GBS formation is proposed.