Negative differential resistance as a critical indicator for the discharge capacity of lithium-oxygen batteries

• Published in: Nature communications Vol. 10; no. 1; pp. 1 - 9
• Main Authors: Hase, Yoko, Komori, Yasuhiro, Kusumoto, Takayoshi, Harada, Takashi, Seki, Juntaro, Shiga, Tohru, Kamiya, Kazuhide, Nakanishi, Shuji
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 05.02.2019; Nature Publishing Group; Nature Portfolio
• Subjects: 140/133; 147/135; 639/638/161/891; 639/638/440/94; Batteries; Cathodes; Chemical reduction; Discharge; Disproportionation; Humanities and Social Sciences; Lithium; Lithium batteries; Lithium oxides; multidisciplinary; Oxygen; Oxygen reduction reactions; Peroxide; Science; Science (multidisciplinary); Stability
• ISSN: 2041-1723; 2041-1723
• DOI: 10.1038/s41467-019-08536-z

In non-aqueous lithium-oxygen batteries, the one-electron reduction of oxygen and subsequent lithium oxide formation both occur during discharge. This lithium oxide can be converted to insulating lithium peroxide via two different pathways: a second reduction at the cathode surface or disproportionation in solution. The latter process is known to be advantageous with regard to increasing the discharge capacity and is promoted by a high donor number electrolyte because of the stability of lithium oxide in media of this type. Herein, we report that the cathodic oxygen reduction reaction during discharge typically exhibits negative differential resistance. Importantly, the magnitude of negative differential resistance, which varies with the system component, and the position of the cathode potential relative to the negative differential resistance determined the reaction pathway and the discharge capacity. This result implies that the stability of lithium oxide on the cathode also contributes to the determination of the reaction pathway. Understanding the fundamental chemistry in Li-O 2 battery holds importance to the development of superior energy devices. Here the authors report that the oxygen reduction reaction in Li-O 2 battery exhibits negative differential resistance, which can work as an indicator to the reaction pathway.