Kinetic Evidence for the Participation of a Diatomic Oxygen Species in Vapor-Phase Oxidation of Butadiene over Silver Catalyst
The participation of an adsorbed diatomic oxygen species in the oxidation of butadiene with O2 or N2O to maleic anhydride over silver catalyst was confirmed by the following finding: reaction order with respect to O2 or N2O is 0.83 or 1.95, respectively, whereas that to butadiene is negative.
Saved in:
| Published in | Bulletin of the Chemical Society of Japan Vol. 51; no. 10; pp. 3061 - 3062 |
|---|---|
| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
The Chemical Society of Japan
01.10.1978
|
| Online Access | Get full text |
Cover
Loading…
| Summary: | The participation of an adsorbed diatomic oxygen species in the oxidation of butadiene with O2 or N2O to maleic anhydride over silver catalyst was confirmed by the following finding: reaction order with respect to O2 or N2O is 0.83 or 1.95, respectively, whereas that to butadiene is negative. |
|---|---|
| ISSN: | 0009-2673 1348-0634 |
| DOI: | 10.1246/bcsj.51.3061 |