Development of high efficiency silica coated β-cyclodextrin polymeric adsorbent for the removal of emerging contaminants of concern from water

• Published in: Journal of hazardous materials Vol. 273; pp. 146 - 154
• Main Authors: Bhattarai, Bikash, Muruganandham, M., Suri, Rominder P.S.
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier B.V 30.05.2014; Elsevier
• Subjects: Adsorption; Applied sciences; Benzhydryl Compounds - chemistry; beta-Cyclodextrins - chemistry; Caprylates - chemistry; Chemical engineering; Cyanates - chemistry; Emerging contaminant; Epichlorohydrin - chemistry; Estradiol - chemistry; Exact sciences and technology; Fluorocarbons - chemistry; Hybrid adsorbent; Phenols - chemistry; Pollution; Polymers - chemistry; Propylamines; Silanes - chemistry; Silicon Dioxide - chemistry; Water Pollutants, Chemical - chemistry; Water Purification - methods; Water treatment; β-cyclodextrin; Water treatment; Emerging contaminant; Hybrid adsorbent; Adsorption; β-cyclodextrin; Steroid; Thermogravimetry; 17β-Estradiol; Adsorption capacity; Crosslinking; Endocrine disruptor; Nitrogen; Thermal stability; Operating conditions; Bisphenol A; Pollution; Transmission electron microscopy; Batchwise; Loading
• ISSN: 0304-3894; 1873-3336
• DOI: 10.1016/j.jhazmat.2014.03.044

•Hybrid adsorbent preparation, optimization and characterization.•Emerging contaminants removal.•Highly efficient, thermally stable and regenerable adsorbent.•More efficient than commercially available and commonly used granular activated carbon F400 for the removal of 17β-estradiol. This article reports the removal of several emerging contaminants (ECs) from water using novel adsorbent comprising of β-cyclodextrin (β-CD) coated on silica. Fourteen different adsorbents were synthesized under different experimental conditions using two different crosslinking agents (hexamethylene diisocyanate (HMDI) and epichlorohydrin (EPI)) and co-polymers (glycidoxypropyl trimethoxysilane (GPTS) and aminopropyl triethoxysilane (APTES). The adsorption capacities of the synthesized adsorbents were initially evaluated using 17β-estradiol, perfluorooctanoic acid (PFOA), and bisphenol-A (BPA) as adsorbates. The adsorbent prepared by using HMDI as crosslinking agent with DMSO as solvent was observed to perform the best, and removed more than 90% of 17β-estradiol, PFOA, and BPA. Furthermore, the β-CD loading on the ECs removal was studied which showed that the adsorbate removal increases with increase in loading of β-CD on the substrate. The best adsorbent was resynthesized in seven batches and its performance was reproducible for the removal of ten steroid hormones. The adsorbent showed very good regeneration potential for four successive adsorption–regeneration cycles to remove steroid hormones and PFOA. A plausible mechanism of adsorption is proposed. The synthesized best adsorbent is characterized using FTIR, HR-TEM, TGA and nitrogen adsorption analysis. The TGA results showed that the adsorbent has thermal stability of upto 300°C.