2-[3-(2-Aminoethylsulfanyl)propylsulfanyl]ethanamine Bearing Dansyl Subunits: An Efficient, Simple, and Rapid Fluorometric Sensor for the Detection of Mercury(II) Ions

A novel fluorometric sensor possessing two dansyl moieties based on 2-[3-(2-aminoethylsulfanyl)propylsulfanyl]ethanamine 1 was prepared by a wady synthetic approach using a conventional two-step synthesis I exhibits highly sensitive and selective on-off Hg2+ fluorescence quenching behavior in aqueou...

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Bibliographic Details
Published inChemistry letters Vol. 39; no. 10; pp. 1099 - 1101
Main Authors Wanichacheva, Nantanit, Kamkaew, Anyanee, Watpathomsub, Supranee, Lee, Vannajan Sanghiran, Grudpan, Kate
Format Journal Article
LanguageEnglish
Published TOKYO Chemical Soc Japan 05.10.2010
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Summary:A novel fluorometric sensor possessing two dansyl moieties based on 2-[3-(2-aminoethylsulfanyl)propylsulfanyl]ethanamine 1 was prepared by a wady synthetic approach using a conventional two-step synthesis I exhibits highly sensitive and selective on-off Hg2+ fluorescence quenching behavior in aqueous acetonitrile solutions and is shown to discriminate various competing metal ions such as Cu2+, Ag+, Ca2+, Mn2+, Zn2+, Ba2+, Cd2+, Co2+, Na+, and K+ exhibiting a detection limit of 7 nM or 1.4 ppb with a working range of 1.8-15 ppb
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2010.1099