Optical birefringence of Zn nanoparticles embedded in silica induced by swift heavy-ion irradiation

• Published in: Optics express Vol. 22; no. 24; pp. 29888 - 29898
• Main Authors: Amekura, H, Okubo, N, Ishikawa, N
• Format: Journal Article
• Language: English
• Published: United States 01.12.2014
• Subjects: Birefringence; Heavy Ions; Metal Nanoparticles - chemistry; Metal Nanoparticles - ultrastructure; Radiation; Silicon Dioxide - chemistry; Spectrum Analysis; Zinc - chemistry
• ISSN: 1094-4087; 1094-4087
• DOI: 10.1364/oe.22.029888

Zn nanoparticles (NPs) embedded in a silica matrix subjected to irradiation with swift heavy ions of 200 MeV Xe¹⁴⁺ have been found to undergo shape elongation from spheres to prolate-spheroids while maintaining the major axes of the NPs in parallel alignment. The directionally-aligned Zn spheroids enable acquisition of optical properties, such as linear dichroism and birefringence. In this paper, the birefringence of the Zn spheroids was evaluated by the crossed-Nicols (XN) transmittance, where a sample was inserted between a pair of optical polarizers that were set in an orthogonal configuration. Linearly-polarized light aligned by the first polarizer was transformed to an elliptic polarization by the birefringence of the Zn spheroids. The existence of the birefringence was confirmed by the non-zero transmittance of the second polarizer in the orthogonal configuration. The sample irradiated with a fluence of 5.0 × 10¹³ ions/cm² exhibited a maximum XN transmittance of 2.1% at a photon energy of ~4 eV. The XN transmission was observed down to a fluence of 1.0 × 10¹² ions/cm², but reduced below the detection limit at a fluence of 1.0 × 10¹¹ ions/cm². The possible application of the elongated Zn NPs as a polarizer with nanometric thickness working in the near- and mid-ultraviolet region is discussed.