A green way to simultaneously enhance the mechanical, flame retardant and anti-ultraviolet aging properties of polylactide composites by the incorporation of tannic acid derivatives

• Published in: Polymer degradation and stability Vol. 196; p. 109831
• Main Authors: Qiu, Shuang, Sun, Jun, Li, Hongfei, Gu, Xiaoyu, Fei, Bin, Zhang, Sheng
• Format: Journal Article
• Language: English
• Published: London Elsevier Ltd 01.02.2022; Elsevier BV
• Subjects: Biodegradability; Biodegradable; Composite materials; degradation; durability; Flame retardant; Flame retardants; Flammability; Mechanical properties; petroleum; pollution; Polylactic acid; Polylactic acid (PLA); Polymers; Product safety; Reinforcement; Service life; Tannic acid; tannins; Tensile strength; Ultraviolet radiation; UV-resistance; Flame retardant; Reinforcement; Biodegradable; Polylactic acid (PLA); UV-resistance
• ISSN: 0141-3910; 1873-2321
• DOI: 10.1016/j.polymdegradstab.2022.109831

•The BA-TA-MEL was directly synthesized through a one-pot method without organic solvent.•5%BA-TA-MEL imparted a desirable UL-94 V-0 rating flame retardancy to PLA.•The incorporation of BA-TA-MEL significantly improved the UV resistance capacity of PLA.•BA-TA-MEL had a reinforcing effect on PLA and improved its mechanical properties. Polylactic acid (PLA), characterized by its biodegradability, easy processing, and environmental friendliness, is regarded as one of the ideal substitutes for petroleum-based polymers. But, the flammability and UV light sensitivity of PLA often impact the safety and service life of its products. In this study, a bio-based additive (BA-TA-MEL) is synthesized via a one-pot method and used as a flame-retardant and anti-UV agent for PLA. The results show that PLA/5%BA-TA-MEL can achieve the desired V-0 degrade in the UL-94 test and an LOI value of 27.1%. Moreover, the PLA/5%BA-TA-MEL exhibits brilliant UV resistance, which increases the UPF to 290.4 from 0.4 of pure PLA. The BA-TA-MEL acts as a rigid particle in the matrix, effectively enhancing the tensile strength of materials. The current work develops a new approach to preparing biodegradable material with excellent performance and extended life to reduce the environmental pressure and pollution caused by petroleum-based plastics. [Display omitted]