Electrically conducting palladium selenide (Pd4Se, Pd17Se15, Pd7Se4) phases: synthesis and activity towards hydrogen evolution reaction

Electrically conducting, continuous films of different phases of palladium selenides are synthesized by the thermolysis of single source molecular precursors. The films are found to be adherent on flat substrates such as glass, indium tin oxide and glassy carbon and are stable under electrochemical...

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Published inChemical communications (Cambridge, England) Vol. 52; no. 1; pp. 206 - 209
Main Authors Kukunuri, Suresh, Austeria, P Muthu, Sampath, S
Format Journal Article
LanguageEnglish
Published England 01.01.2016
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Summary:Electrically conducting, continuous films of different phases of palladium selenides are synthesized by the thermolysis of single source molecular precursors. The films are found to be adherent on flat substrates such as glass, indium tin oxide and glassy carbon and are stable under electrochemical conditions. They are electrocatalytically active and in particular, for hydrogen evolution reaction. Catalytic activities with low Tafel slopes of 50-60 mV per decade are observed.
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ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc06730h