Role of field-induced nanostructures, zippering and size polydispersity on effective thermal transport in magnetic fluids without significant viscosity enhancement

• Published in: Journal of magnetism and magnetic materials Vol. 444; pp. 29 - 42
• Main Authors: Vinod, Sithara, Philip, John
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 15.12.2017; Elsevier BV
• Subjects: Aggregates; Capping; Computational fluid dynamics; Conduction heating; Conductive heat transfer; Cooling; Electron microscopy; Energy harvesting; Ferrofluids; Field induced nanostructure; Fourier transforms; Heat transfer; High aspect ratio; Light diffraction; Liquid layering; Magnetic fields; Magnetic fluids; Magnetic properties; Nanofluids; Nanostructure; Nanostructured materials; Particulate composites; Photon correlation spectroscopy; Polydispersity; Rheological properties; Studies; Thermal conductivity; Thermal energy; Thermal properties; Tunable thermal conductivity; Viscosity; X-ray scattering; Thermal properties; Liquid layering; Field induced nanostructure; Tunable thermal conductivity; Magnetic fluids
• ISSN: 0304-8853; 1873-4766
• DOI: 10.1016/j.jmmm.2017.07.100

Thermal pattern of electronic device with and without magnetic field, the corresponding photographs of ferrofluids and schematic of particle arrangements. [Display omitted] •Very high thermal conductivity (k) to viscosity ratio is achieved in magnetic fluids under certain conditions.•Magneticfluids with smaller polydispersity gives larger k enhancement.•High density interfacial capping on nanoparticles enable effective heat transport.•Large number of space filling linear aggregates with high aspect ratio is ideal for effective heat transport.•Zippering of linear chains considerably reduces the thermal transport. Magnetic nanofluids or ferrofluids exhibit extraordinary field dependant tunable thermal conductivity (k), which make them potential candidates for microelectronic cooling applications. However, the associated viscosity enhancement under an external stimulus is undesirable for practical applications. Further, the exact mechanism of heat transport and the role of field induced nanostructures on thermal transport is not clearly understood. In this paper, through systematic thermal, rheological and microscopic studies in ‘model ferrofluids’, we demonstrate for the first time, the conditions to achieve very high thermal conductivity to viscosity ratio. Highly stable ferrofluids with similar crystallite size, base fluid, capping agent and magnetic properties, but with slightly different size distributions, are synthesized and characterized by X-ray diffraction, small angle X-ray scattering, transmission electron microscopy, dynamic light scattering, vibrating sample magnetometer, Fourier transform infrared spectroscopy and thermo-gravimetry. The average hydrodynamic diameters of the particles were 11.7 and 10.1nm and the polydispersity indices (σ), were 0.226 and 0.151, respectively. We observe that the system with smaller polydispersity (σ=0.151) gives larger k enhancement (130% for 150G) as compared to the one with σ=0.226 (73% for 80G). Further, our results show that dispersions without larger aggregates and with high density interfacial capping (with surfactant) can provide very high enhancement in thermal conductivity, with insignificant viscosity enhancement, due to minimal interfacial losses. We also provide experimental evidence for the effective heat conduction (parallel mode) through a large number of space filling linear aggregates with high aspect ratio. Microscopic studies reveal that the larger particles act as nucleating sites and facilitate lateral aggregation (zippering) of linear chains that considerably reduces the number density of space filling linear aggregates. Our findings are very useful for optimizing the heat transfer properties of magnetic fluids (and also in composite systems consisting of CNT, graphene etc.) for the development of next generation microelectronic cooling technologies, thermal energy harvesting and magnetic fluid based therapeutics.