High-efficiency phosphorus/nitrogen-containing flame retardant on epoxy resin

• Published in: Polymer degradation and stability Vol. 187; p. 109544
• Main Authors: Wang, Donghui, Liu, Quanyi, Peng, Xiaoliang, Liu, Chuanbang, Li, Zekun, Li, Zhifa, Wang, Rui, Zheng, Penglun, Zhang, Hui
• Format: Journal Article
• Language: English
• Published: London Elsevier Ltd 01.05.2021; Elsevier BV
• Subjects: Benzoxazines; Bisphenol A; combustion; Condensed phase; crosslinking; degradation; epoxides; Epoxy resin; Epoxy resins; Flame retardancy; Flame retardants; Gas phase; Heterocyclic compounds; Hydroxyl groups; Lower phosphorus content; Nitrogen; Phosphorus; polymers; Epoxy resin; Flame retardancy; Condensed phase; Gas phase; Lower phosphorus content
• ISSN: 0141-3910; 1873-2321
• DOI: 10.1016/j.polymdegradstab.2021.109544

•A novel phosphorus/nitrogen-containing hybrid containing phosphophenanthrene and nitrile groups•It significantly improved both thermal stability and flame retardancy of epoxy resins at low phosphorus content.•The flame-retardant mechanism acted in both gas phase and condensed phase.•Limiting oxygen index of epoxy resin increased to 41.2%. A phosphorus/nitrogen-containing compound (named DOPO-BAPh) was synthesized via the graft reaction between 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) and bisphenol A bis(phthalonitrile) containing benzoxazine. The flame retardancy of DOPO-BAPh was investigated on epoxy resin (EP). The results showed that DOPO-BAPh catalyzed the curing reaction of due to the phenolic hydroxyl groups in the structure. The nitrile group in DOPO-BAPh was self-cured in EP to form cross-linked networks containing aromatic heterocycles, further enhancing the stability of the char layer formed after combustion. The introduction of DOPO-BAPh strengthened flame retardancy of the EP. With only 0.26 wt.% phosphorus of loading level, the modified EP reached an LOI value of 35.8% and obtained V-0 rating in UL-94 testing. And DOPO-BAPh exhibited char-forming ability during the decomposition. Besides, the DOPO-BAPh showed flame-retardant activity in both the gas and condensed phases.