Very short asymmetric synthesis of (1 S, 3 S, 5 R)-1,3-dimethyl-2,9-dioxabicyclo[3.3.1]nonane via tandem enantioselective reactions promoted by one chiral borane

A very short asymmetric synthesis of the title compound has been realized with a chiral borane-mediated aldol reaction strategy with high enantio- and diastereoselectivities. Graphic

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Bibliographic Details
Published inTetrahedron letters Vol. 36; no. 16; pp. 2821 - 2822
Main Authors Kiyooka, Syun-ichi, Kaneko, Yuichi, Harada, Yumi, Matsuo, Takao
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 17.04.1995
Elsevier
Subjects
Chemistry
Chemistry, Organic
derivatives
insect attractants
nonane
Physical Sciences
Science & Technology
stereochemistry
synthesis
Trypodendron lineatum
COMPONENTS
(-)-(1R,3R,5S)-1,3-DIMETHYL-2,9-DIOXABICYCLO<3.3.1>NONANE
STEREOSELECTIVE SYNTHESIS
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Summary:A very short asymmetric synthesis of the title compound has been realized with a chiral borane-mediated aldol reaction strategy with high enantio- and diastereoselectivities. Graphic
ISSN:0040-4039
1873-3581
DOI:10.1016/0040-4039(95)00406-3