Comparing the effect of nanofillers as thermal stabilizers in low density polyethylene

• Published in: Polymer degradation and stability Vol. 94; no. 1; pp. 39 - 48
• Main Authors: García, Nuria, Hoyos, Mario, Guzmán, Julio, Tiemblo, Pilar
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier Ltd 2009; Elsevier
• Subjects: Applied sciences; Composites; Compounding ingredients; Exact sciences and technology; Forms of application and semi-finished materials; LDPE; Montmorillonite; Nanocomposite; Polymer industry, paints, wood; Sepiolite; Silica nanoparticles; Stabilizers (antioxydants, antiozonants, etc.); Technology of polymers; Thermal degradation; Silica nanoparticles; Nanocomposite; Montmorillonite; LDPE; Sepiolite; Thermal degradation; Clay; Heat stabilizer; Thermooxidative degradation; Dispersion reinforced material; Thermal stabilization; Experimental study; Silica; Composite material; Thermal stability; Polymer filler interaction; Thermal properties; Additive; Low density ethylene polymer; Reaction mechanism; Olefin polymer; Kinetics
• ISSN: 0141-3910; 1873-2321
• DOI: 10.1016/j.polymdegradstab.2008.10.011

A study of the thermal degradation under inert and oxidative conditions of LDPE and three 5-wt% nanocomposites has been performed. The bases of comparison were the geometries of the nanofillers (spherical, fibrous and laminar) and the sample thickness. Homogeneous and well-dispersed materials were obtained with the three nanoparticles, ensuring a relevant comparative analysis. The thermal degradation curves obtained from TGA under nitrogen flow did not show significant differences in behaviour within the nanocomposites and the reference LDPE. However, the results for the thermo-oxidation study showed a strong stabilization effect for both fibrous and laminar silicates, but not for the spherical silica nanoparticles. A kinetic study of the degradation under isothermal conditions showed that the nanocomposites made from fibrous and laminar silicates degraded following the mechanisms observed for thin films independent of the sample thickness. These results suggested the occurrence of a protective layer against thermo-oxidation on the film surface. Chemical analysis of the degraded surfaces by IR and EDX measurements gave data to explain these differences in behaviour.